Electrochemical synthesis of inorganic and organic compounds with Boron-Doped diamond electrodes
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The electrochem. oxidn. of EDTA was studied at boron-doped diamond (BDD) electrodes. Cyclic voltammetry in the potential region of water stability showed that EDTA is oxidized in an irreversible 2-electron-transfer mechanism. No fouling phenomena were noti ...
The concept of non-diamond sp2 impurity states as charge transfer mediators on boron-doped diamond (BDD) surface was suggested as an explanation for the electrochem. behavior of synthetic diamond-based electrodes. To verify this concept, graphite particles ...
The methoxylation of p-tert-butyltoluene (TBT) in CH3OH-H2SO4-H2O soln. has been investigated on graphite and boron-doped diamond (BDD) anodes. Different reaction intermediates have been found on BDD and graphite. In fact BDD electrodes favor the formation ...
Electrochem. and phys. properties of polycryst. B-doped diamond electrodes with a metallic conduction grown by MPCVD and HFCVD were studied with the goal to use them as cathodes, for the electrochem. redn. of nitrate in neutral solns. All electrodes contai ...
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A newly designed thin-layer STM (TLSTM) technique is presented based on a microfabricated probe combining an electrolytic STM probe with an annular iridium oxide microelectrode operating as a potential-controlled generator or scavenger of H+. This TLSTM co ...
The electrochem. behavior of synthetic B-doped diamond thin-film electrode (BDD) was studied in acid media contg. 4-chlorophenol (4-CP) by cyclic voltammetry, chronoamperometry, and bulk electrolysis. The results showed that in the potential region of supp ...
