Coherence transfer in nuclear magnetic resonance by selective homonuclear Hartmann-Hahn correlation spectroscopy
Graph Chatbot
Chattez avec Graph Search
Posez n’importe quelle question sur les cours, conférences, exercices, recherches, actualités, etc. de l’EPFL ou essayez les exemples de questions ci-dessous.
AVERTISSEMENT : Le chatbot Graph n'est pas programmé pour fournir des réponses explicites ou catégoriques à vos questions. Il transforme plutôt vos questions en demandes API qui sont distribuées aux différents services informatiques officiellement administrés par l'EPFL. Son but est uniquement de collecter et de recommander des références pertinentes à des contenus que vous pouvez explorer pour vous aider à répondre à vos questions.
A soln. is presented to the problem of phase dispersion in the resultant magnetization for pulses used for high-resoln. NMR work by demonstrating how a Gaussian pulse having an on-resonance flip angle of 270 Deg has much improved phase properties over the ...
An anal. was made of the effects of nonexponential transverse relaxation during the free precession periods of 2-dimensional NMR expts. The presence of cross-correlation between various interactions that cause relaxation, such as chem. shift anisotropy and ...
Procedures are described for automated anal. of two-dimensional NMR spectra correlating the chem. shifts of carbon-13 with the shifts of neighbor protons that are directly attached to the carbon-13 nuclei and with remote protons that have scalar couplings ...
Cross-correlation between proton chem. shift anisotropy and proton-proton dipolar interactions is shown to be an important relaxation mechanism. Cross-correlation leads to a partial conversion of Zeeman order into longitudinal two-spin order. The build-up ...
In applications to systems with resolved scalar couplings, the 2-dimensional exchange expt. (NOESY: nuclear Overhauser effect spectroscopy) can provide greatly increased information if the flip angles of the 2 pulses that precede and follow the mixing inte ...
The use is described of pattern recognition techniques to analyze folded (in w1) 2-dimensional NMR spectra obtained by using the COSY (correlation spectroscopy) technique. A pattern recognition procedure (P. and B., 1986) relying on the comparison of patte ...
Self-convolution and symmetry mapping were used to analyze proton multiplets in two-dimensional NMR spectra of the triterpene, obtusifolione (I). [on SciFinder (R)] ...
Computer-supported anal. of two-dimensional correlation spectra encounters a no. of obstacles which are due, in the simplest case, to insufficient digital resoln., and, in more severe cases, to fundamental ambiguities in multiplet patterns. Various strateg ...
A novel spin-echo expt. is proposed that uses semiselective Gaussian pulse cascades for refocusing in systems with homonuclear couplings. The expt. allows one to obtain evdience of differential T2 effects due to cross-correlation of proton chem. shift anis ...