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Higher Rydberg states of NO trapped in rare gas matrixes were studied by inducing Rydberg-Rydberg transitions from the lowest A2S+ (3ss) Rydberg state and detecting its fluorescence depletion. This technique unravels Rydberg states, which cannot be accesse ...
The cage-induced stabilization of fragments in excited electronic states following the UV-dissocn. of ICN in cryogenic matrixes is discussed. Emission spectra recorded upon ~A-band excitation of ICN in solid Ne, Ar and Kr exhibit a long progression of broa ...
Rydberg-Rydberg transitions are induced by absorption from the lowest Rydberg state of NO A 2S+ (3ss) in Ar matrixes, which is excited by an ArF laser at 193.3 nm. The depopulation of the A(v = 0) level to higher Rydberg states is probed by depletion of it ...
Structural dynamics in solid hydrogens is impulsively triggered by femtosecond excitation of the lowest Rydberg state of the NO impurity. The resulting charge redistribution induces a local radial deformation of the medium ("bubble" formation) around the ...
Structural dynamics in semi-quantum and quantum solids (Ne, H2 and D2) is reported, and compared to results in classical solids such as Ar. The structural dynamics is driven by excitation of the lowest Rydberg state of the NO impurity. The resulting charge ...
State-selected spectra of the OH stretch overtones of methanol in the range of upsilon(1) = 3-8 reveal spectral splittings and broadenings that result from vibrational couplings within the molecule. We employ a two-color excitation technique in which an in ...
Fully rotationally resolved spectra of the two lowest-frequency bands ~the origin (00 0 ) and the inversion (140 1) band! of the S1(n p*)ÃS0 transition of jet-cooled (Trot'6 K) acetaldehyde, CH3CHO, have been recorded with a resolution of '0.01 cm21 using ...
The dynamics of non-polar electronic solvation has been studied on a model system consisting of NO-doped solid Ar. Excitation of the lowest Rydberg state A(3ss) of NO leads to formation of an electronic 'bubble', which has been studied by femtosecond pump- ...
This paper describes a new spectroscopic technique which uses photodissociation to detect pure rotational transitions in highly excited vibrational energy levels of the ground electronic state. This method has initially been applied to the (HOCl)-Cl-35 mol ...
