a-Fluoro- and a,a-difluoroalkanals by substitution of vicinal bromofluoroalkanes and subsequent Pummerer rearrangement
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Amatoxins are ribosomally synthesized and post-translationally modified bicyclic octapeptides biosynthesized by the deadly basidiomycete fungus Amanita phalloides. Amongst this group, alpha-amanitin is the most widely known toxin and is currently under inv ...
a-Amino ketones and 1,2-amino alcohols are important structural motifs in organic chemistry, that
can be observed in natural products, pharmaceutically and bioactive compounds. For these reasons,
they constitute privileged targets for the development of ne ...
The most prevalent single-nucleotide substitution (SNS) found in cancers is a C-to-T substitution in the CpG motif. It has been proposed that many of these SNSs arise during organismal aging, prior to transformation of a normal cell into a precancerous/can ...
Azetidinyl substituents have been recently used to improve the fluorescence quantum yield of several classes of fluorophores. Herein, we demonstrate that other useful photochem. processes can be modulated using this strategy. In particular, we prepd. and m ...
Ferroelectric orthorhombic lead metaniobate (PbNb2O6) is known to be metastable with respect to the thermodynamically stable nonferroelectric rhombohedral polymorph. The high-temperature tetragonal to low temperature rhombohedral phase transition is recons ...
Methane can be an alternative fuel for vehicular usage provided that new porous materials are developed for its efficient adsorption-based storage. Herein, we search for materials for this application within the family of diamond analogues. We used density ...
This paper describes a new design of the multipurpose cryptographic primitive ARMADILLO3 and analyses its security. The ARMADILLO3 family is oriented on small hardware such as smart cards and RFID chips. The original design ARMADILLO and its variants were ...
The reaction of tetranitromethane with B-alkylcatecholboranes leads to the formation of unusual dinitrooxime ethers. A tentative mechanism is provided, which suggests the involvement of extremely fast addition of alkyl radicals to tetranitromethane. The su ...
This paper investigates an isolated setting of the lexical substitution task of replacing words with their synonyms. In particular, we examine this problem in the setting of subtitle generation and evaluate state of the art scoring methods that predict the ...
This paper investigates an isolated setting of the lexical substitution task of replacing words with their synonyms. In particular, we examine this problem in the setting of subtitle generation and evaluate state of the art scoring methods that predict the ...
