Publication
Meta- rather than ortho-directed metalations: Buttressing effects prejudicing the proton abstraction from (2,6-dihalophenyl)silanes
Publications associées (65)
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The deprotonation energies of benzene, fluorobenzene, all di-, tri-, and tetrafluorobenzenes, pentafluorobenzene, chlorobenzene, all di-, tri-, and tetrachlorobenzenes, and pentachlorobenzene have been calcd. at various levels of second-order Moller-Plesse ...
2005Fluorine-substituted aryllithiums
Among other things, the present thesis work aimed at a rational and maximal structure proliferation. Simple arenes or heteroarenes were functionalized regioselectively through organometallic intermediates, which then may be combined with any electrophile t ...
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2004The preparation of organolithium reagents and intermediates
A review. Only the most important methods for the generation of organometallic reagents and intermediates are covered in this review. This holds for the reductive insertion of Li into org. halides, the permutational interconversion of org. halides with org ...
Wiley2004