1H, 19F-HOESY and PGSE diffusion studies on ionic liquids: The effect of co-solvent on structure
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The ionic liquid crystal [C12-mim]Cl has been doped with 5 mol% europium nitrate and the photophysical properties of both the ionic liquid and the trivalent europium ion have been monitored with respect to temperature in the range of 248 to +120 uC. The re ...
The mol. vol. Vm (i.e., the sum of the ionic vols. Vion of the constituent ions) of an ionic liq. (IL) in combination with an anion-dependent empirical relationship is all one needs to predict phys. properties such as viscosity, cond., and d. of [N(CN)2]-, ...
The IR and Raman spectra and conformations of the ionic liquid 1-ethyl-3-methyl-1H-imidazolium tetrafluoroborate, [EMIM][BF4] (6), were analyzed within the framework of scaled quantum mechanics (SQM). It was shown that SQM successfully reproduced the spect ...
Chloro- and hydrido-complexes of ruthenium(II) with potassium (4-diphenylphosphino)benzenesulfonate (pTPPMS) were prepared and their properties were compared with those of the related complexes of (3-diphenylphosphino)benzenesulfonates. An X-ray crystal st ...
A new macrocyclic ligand, L3, has been synthesised, based on the cyclen framework grafted with three phenacyl light-harvesting groups and a C5-alkyl chain bearing a carboxylic acid function as a potential linker for biological material. Acidity constant ...