Modeling of heavy metals adsorption to a chelating resin in a fluidized bed reactor
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Monitoring, control and optimization of chemical reaction systems often requires in-depth analysis of the underlying reaction mechanisms. This dissertation investigates appropriate tools that facilitate the analysis of homogeneous and gas-liquid reaction s ...
A stirred-tank reactor was built with the objective of rapid and accurate temperature control in the reaction vessel. A first-principles heat transfer model was developed for the jacketed batch system, with the jacket inlet temperature used to control the ...
The possibility to increase the performance (productivity or selectivity) of a chemical reactor by using periodic variations of reaction parameters (e.g. reactant concentration or temperature) has been theoretically envisaged since the beginning of the 70t ...
Two types of stainless steel microstructured reactors for catalytic gas-phase reactions have been developed and characterized with respect to their thermal behaviour under non-stationary temperature conditions. One of the reactors used (FTC-I) allowed peri ...
The PhD thesis deals with the optimization of the reaction calorimetry technique to monitor chemical reactions in supercritical fluids. The aim is to develop this thermal analysis technique to monitor the heat released by a chemical reaction in a high pres ...
Compliance with the U.S. drinking water standard for arsenic (As) of 10 μg L-1 is required in January 2006. This will necessitate implementation of treatment technologies for As removal by thousands of water suppliers. Although a variety of such technologi ...
Models of chemical reactors can be quite complex as they include information regarding the reactions, the transfer of species between phases, the transfer of energy, and the inlet and outlet flows. Furthermore, the effects of the various phenomena are quit ...
Multi-objective optimisation (MOO) of super-structured process designs are expensive in CPU- time because of the high number of potential configurations and operation conditions to be calculated. Thus single process units are generally represented by simpl ...
Epoxidized soybean oil (ESBO) is produced in industry by reacting soybean oil, at 60-70 degrees C, with hydrogen peroxide in the presence of formic or acetic acid. A small amount of sulphuric or phosphoric acid is necessary to catalyze the oxidation of the ...
Conjugated kinetic and thermodynamic modeling is suggested as a suitable approach to identify a novel process window (NPW) for the intensification of slow reversible reactions. The aqueous Kolbe-Schmitt synthesis of beta-resorcylic acid is taken as a model ...
