General and Practical Formation of Thiocyanates from Thiols

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Investigation of femtosecond laser-tuned thermomechanical properties of fused silica

Pieter Vlugter

The thermomechanical properties of materials are among the most important properties for designing precision instruments, in particular for devices seeking high-dimensional stability, invariant temperature-elastic properties or low thermoelastic losses. De ...

EPFL2020

A Kinetic Map of the Homomeric Voltage-Gated Potassium Channel (Kv) Family

Henry Markram, Rajnish Ranjan, Emmanuelle Logette, Enrico Scantamburlo, Mirjia Herzog, Valérie Buchillier, Michela Marani, Valérie Tâche

The voltage-gated potassium (Kv) channels, encoded by 40 genes, repolarize all electrically excitable cells, including plant, cardiac, and neuronal cells. Although these genes were fully sequenced decades ago, a comprehensive kinetic characterization of al ...

2019

Tailoring thermal properties of functional materials

Xavier François Mettan

Thermal conductivity (k) plays an essential role in functional devices. In some cases, high value is required to transfer heat efficiently. In others, low k assists in maintaining a temperature gradient necessary for device operation. It is profitable to d ...

EPFL2019

Computational studies of the structural and optical properties of organic-inorganic lead halide perovskites

Ariadni Boziki

The rapid rise of organic-inorganic lead halide perovskites has amazed the photovoltaic community. As the efficiency race continues for this revolutionary class of light-harvesting materials, many questions on the structural, electronic and optical propert ...

EPFL2019

Effective conductivity of porous ceramics in a radiative environment

Sophia Haussener, Clemens Gregor Suter, Jérémy Raphaël Mora-Monteros

The knowledge of the effective thermal conductivity, taking into account conduction and radiation, is crucial for the accurate prediction of the thermal behavior of porous foams, especially in an environment where radiation is dominating. We present a comb ...

2020

Application of Hypervalent Iodine Reagents for Novel Cysteine Labeling

Romain Gaëtan Tessier

Selective functionalization of peptides and proteins has always been a valuable tool for the study and manipulation of biological processes. In this context, cysteines are of particular interest. Their intrinsic high nucleophilicity makes these amino acids ...

EPFL2019

Reactivity of Bioinspired Magnesium-Organic Networks under CO2 and O-2 Exposure

Klaus Kern, Magalí Alejandra Lingenfelder, Bart Willem Stel, Fernando Pablo Cometto, Daniel Eduardo Hurtado Salinas

Photosynthesis is the model system for energy conversion. It uses CO2 as a starting reactant to convert solar energy into chemical energy, i.e., organic molecules or biomass. The first and rate-determining step of this cycle is the immobilization and activ ...

2019

Nanoscale Lithography and Thermometry with Thermal Scanning Probes

Samuel Tobias Howell, Samuel Zimmermann

Thermal scanning probe lithography (t-SPL) is an advanced lithography technique in which a heated atomic force microscope tip locally modifies a sample material. Due to the nanometer-sized tip apex diameter, t-SPL enables patterning of sub-10 nm structures ...

EPFL2018

Coupled Thermo-hydro-Mechanical Effects on Caprock Stability During Carbon Dioxide Injection

Lyesse Laloui, Chao Li

This study presents a numerical investigation of the effects of coupled material properties on the caprock stability. A thermo-hydro-mechanical framework is proposed in order to reproduce the physical processes. The results indicate that for a given geomet ...

2017

Room Temperature as a Goldilocks Environment for CH3NH3PbI3 Perovskite Solar Cells: The Importance of Temperature on Device Performance

Wolfgang Richard Tress, Ulf Anders Hagfeldt, Juan-Pablo Correa-Baena, Tor Jesper Jacobsson

Terrestrial applications of solar cells during day-night cycling as well as operation in winter and summer involve substantial temperature variations, which influence the photophysics as well as the charge separation and transport properties in the various ...

American Chemical Society2016

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Room Temperature as a Goldilocks Environment for CH3NH3PbI3 Perovskite Solar Cells: The Importance of Temperature on Device Performance

Wolfgang Richard Tress, Ulf Anders Hagfeldt, Juan-Pablo Correa-Baena, Tor Jesper Jacobsson

American Chemical Society2016