Irradiation-induced disorder in high-T-c cuprates: electronic band structure study

We used thermal neutron irradiation to produce disorder in Bi-2212 single crystals (T-c = 85 K), at a constant carrier density. The irradiated samples were insulators. High-temperature superconductivity with a lower T-c than prior to irradiation could be restored by a low-temperature annealing. We performed angle-resolved photoemission investigation on both unannealed (insulating) and annealed (superconducting) samples in order to study the corresponding changes in electronic structure. We observed a strong suppression of the spectral weight near the Fermi energy with increasing disorder. Our results demonstrate that effects related to disorder cannot be neglected in the interpretation of the spectral properties of cuprates. (C) 1998 Elsevier Science B.V. All rights reserved.

Kinks in the angle resolved photoemission and inelastic x-ray spectra of high temperature superconductors

Jeff Graf

Though the high superconducting transition temperature (Tc) is the most interesting technological aspect of high temperature superconductors, the complex way in which the spin, lattice and electronic degrees of freedom interplay, makes them of the highest scientific interest. This is illustrated by their rich phase diagram characterized by a variety of exotic groundstate including; Mott insulating, pseudogap and high temperature superconductivity. One of the most serious barriers that has prevented our understanding of the mechanism of high temperature superconductors thus far is the lack of information on how low energy Landau quasiparticles result from an organization of real particles. This organization, often colloquially referred to as "dressing", is a fundamental general concept in physics that explains a variety of physical phenomena, such as exotic particle formations and phase transitions. The role of the lattice in this dressing is particularly controversial. Phonons are quanta of lattice vibration energy, and play a crucial role in conventional superconductivity. They provide an attractive interaction allowing the electrons to condensate in superconducting Cooper pairs. However, high temperature superconductivity in the cuprates in achieved through hole doping in an antiferromagnetic Mott insulator. In this case, the antiferromagnetic background, the strong coulomb repulsion and the anisotropic superconducting gap all suggest a marginal role of the phonons. In order to assess experimentally the exact role of the phonon, angle resolved photoemission spectroscopy (ARPES) is the weapon of choice given its unique ability to probe the electronic structure of solids in an energy- and momentum-resolved manner. In this thesis, I will use ARPES to characterize the various form of dressing of the quasiparticles in the high temperature superconductor from the Fermi level all the way to the valence band complex. I'll show that when combined with isotope substitution and inelastic x-rays scattering, the strong electron-phonon interaction can be probed in vivid details. This thesis presents three fundamental results. 1) Using the isotope effect, the important and unusual role of the phonon is demonstrated, as well as the strong interplay between the magnetic and phonic degrees of freedom. 2) Using inelastic scattering, the intriguing interplay between the Fermi surface and the bond stretching phonon is exposed. And 3) By exploring the ARPES data up to high energy, two new energy scales at high binding energy as well as the spectral waterfalls phenomenon are revealed. When all these new elements are considered together, they clearly show the need to consider simultaneously the spin, lattice, Fermi surface topology and electronic degrees of freedom. The spectacular progress in ARPES techniques over the past two decades was critical for these results, and I will present in this thesis our current effort in pushing the techniques even further. In particular I'll present my efforts in building a laser based ARPES setup with a hemispherical analyzer and a spin resolved time of flight analyzer.

EPFL2008

Photoemission studies of thin films grown by pulsed laser deposition

Mike Abrecht

In this thesis I report on the unique novel possibilities offered by combining pulsed laser deposition (PLD) film growth of high temperature superconductors with angle integrated and angle resolved photoemission spectroscopy (PES and ARPES). The originality of the procedure rests on the in situ preparation and transfer of samples, hence by-passing the usual cumbersome cleaving or scraping practices to obtain high quality surfaces suitable for photoemission studies. Photoemission spectroscopy is one of the major experimental techniques to analyze the electronic structure that holds the key to understanding the properties of the high Tc cuprates (copper oxides) for which a complete microscopic theory still needs to materialize. In chapter 1, I introduce these complex copper oxide materials. The vast majority of ARPES measurements on the cuprate superconductors have so far been limited to the easily cleavable Bi2Sr2CaCu2O8+x (BSCCO-2212) single crystals. In chapter 2, I present the principle of an ARPES measurement, and show as an example (obtained in the "traditional way" of cleaving single crystals) a crossover in the electronic response at a special temperature T+>Tc in overdoped samples. In chapter 3, our unique laser ablation set-up, built on site at the Wisconsin Synchrotron Radiation Center (SRC), is introduced. This is followed by reports on film characterization such as transport, crystal and surface properties which enables the optimization of growth parameters. From here on to the end of the thesis, we show that instead of being a competing technique to cleaving samples, in situ growth of films appears to be a complementary one. In particular, our results show that preparing cuprates which contain oxygen chains, like Re-Ba2Cu3O6+x (RBCO-123; R=Y, Nd), for the surface sensitive ARPES measurements is very difficult due to a material intrinsic loss of oxygen near the surface. This, in turn, curbs the photoemission signal near the chemical potential due to the loss of superficial conductivity (chapter 3). Among the cuprates studied, La2-xSrxCuO4 (LSCO) and Bi2Sr2CaCu2O8+x films, however, both exhibit a sharp Fermi step in angle integrated photoemission spectra, indicating a conducting behavior at the surface. Moreover, thanks to using film samples, we were able to study ultra thin cuprates, down to about 1 unit cell (UC), and we were able to induce epitaxial strain in the samples which can remarkably enhance superconductivity. In chapter 4, combining core level, angle integrated valence band photoemission, and x-ray diffraction, we demonstrate that a structural phase transition occurs in the early growth of BSCCO-2212 films on SrTiO3 (STO) substrates, transforming the precursor Bi6O7 natural reactive buffer layer into the BSCCO-2212 structure. This is qualitatively different from the initial growth of YBCO-123 characterized by nucleation of well separated islands. Chapter 5 then presents the main success of our method: the first ever ARPES data on the low energy electronic structure of any high Tc superconductor under strain. In particular, we confirm that the Fermi surface (FS) of LSCO evolves with doping, but changes even more significantly with strain. More specifically, the FS becomes electron-like for in-plane compressed samples (for all doping values x studied, 0.1

EPFL2003

Direct photoemission spectroscopy and electronic properties of in situ grown, strained high-T-c and related oxide films

Mike Abrecht, Dominique Cloëtta, Giorgio Margaritondo, Davor Pavuna, Dusan Vobornik

We have optimized laser ablation thin film deposition and transfer procedures within synchrotron vault, specifically to perform angle-integrated and angle-resolved photoemission spectroscopy (ARPES) on high-T-c and related films without cleaving the samples. However, the chain-containing phases like YBCO-123 easily loose surface oxygen and do not exhibit stable Fermi edge, hence are not suitable for ARPES studies. Direct in situ ARPES studies on strained LSCO-214 films show striking strain effects on the electronic structure. The Fermi surface (FS) of LSCO evolves with doping, yet changes even more significantly with strain. The strain changes the FS topology from hole-like to electron-like, and causes band dispersion along k(x) and the Fermi level crossing before the Brillouin zone boundary, in sharp contrast to the 'usual' flat band remaining approximate to 30 meV below E-F measured on unstrained samples. The associated reduction of the density of states does not diminish the superconductivity; T-c is enhanced in all our strained samples. Implications for the evolving high-T-c theory and studies of nano-engineered film heterostructures are briefly discussed. (C) 2004 Elsevier Ltd. All rights reserved.

2004