Stability and physical properties of alkylsilane and alkylphosphonate self-assembled monolayer (SAM) films on metal oxide substrates characterized at the micro- and nanoscale
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We established the charge and structure of the oil/water interface by combining ?-potential measurements, sum frequency scattering (SFS) and molecular dynamics simulations. The SFS experiments show that the orientation of water molecules can be followed on ...
The average lifetime of an implanted pacemaker or defibrillator cable (lead) is approximately 10 years. One of the main lead failure mechanisms is deterioration of the insulation, which can be caused by chemical, biological, and mechanical processes. Each ...
Capillarity is pivotal to many important technologies, including capillary self-alignment and self-assembly for heterogeneous microsystem integration and packaging. Lateral capillary forces ensuing from perturbed fluid menisci were the object of substantia ...
The corrosion and tribocorrosion of tungsten in 0.01 M H2SO4, without and with the presence of lactic acid and phosphoric acid as chelating agents was studied here. ...
With increasing computer capabilities, numerical modeling of two-phase flows has developed significantly over the last few years. Although there are two main categories, namely 'one' fluid and 'two' fluid methods, the 'one' fluid methods are more commonly ...
Electrochemical and friction measurements during unidirectional sliding tests are used to monitor and to evaluate the tribocorrosion behavior of a passivating material. Tribocorrosion is the interplay between chemical, electrochemical, and mechanical proce ...
A new method based on the Young-Laplace equation for measuring contact angles and surface tensions is presented. In this approach, a first-order perturbation technique helps to analytically solve the Young-Laplace equation according to photographic images ...
Molecular self-assembly at metal surfaces has been recognized as an efficient strategy to create supramolecular nanoarchitectures with promising functionalities. The focus of this thesis lies on the strong electron accepting molecule 7,7,8,8-tetracyanoquin ...
Molecular junctions have been characterized to determine the influence of the metal contact formation in the electron transport process through a single molecule. With inelastic electron tunneling spectroscopy and first-principles calculations, the vibrati ...
Friction and the associated wear are important but still poorly understood phenomena with strong impacts on our every day lives. Several mechanisms, such as plasticity, lattice vibration, and third-body interactions contribute to the dissipation of energy ...