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Solvent Effect on Redox Properties of Hexanethiolate Monolayer-Protected Gold Nanoclusters

Publications associées (33)

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Adsorption and electronic properties of pentacene on thin dielectric decoupling layers

Klaus Kern, Uta Schlickum, Alexander Kabakchiev, Daniel Pablo Rosenblatt, Sebastian Koslowski

With the increasing use of thin dielectric decoupling layers to study the electronic properties of organic molecules on metal surfaces, comparative studies are needed in order to generalize findings and formulate practical rules. In this paper we study the ...

Beilstein Institut2017

Molecular insights in aqueous systems

Yixing Chen

The unique structure and dynamics of the water hydrogen (H)-bond network enable a multitude of structures and chemical reactions in both bulk solutions and at interfaces. The underlying molecular interactions between water and dissolved electrolytes, organ ...

EPFL2017

Nonlinear graphene quantum capacitors for electro-optics

Sina Khorasani, Akshay Koottandavida

Owing to its peculiar energy dispersion, the quantum capacitance property of graphene can be exploited in a two- dimensional layered capacitor configuration. Using graphene and boron nitride, respectively, as the electrodes and the insulating dielectric, a ...

Springer Nature2017

Continuously operated falling film microreactor for selective hydrogenation of carbon-carbon triple bonds

Lioubov Kiwi, Charline Berguerand

Despite significant advances in the fabrication and applications of microreactors for production of chemicals, their use for catalytic reactions remains a challenge, especially in fine chemical synthesis where the selectivity towards the desired product is ...

Elsevier2016

Exploring the aqueous vertical ionization of organic molecules by molecular simulation and liquid microjet photoelectron spectroscopy

Jeremy Samuel Arey, Peter Rudolf Tentscher, Jennifer Guerard

To study the influence of aqueous solvent on the electronic energy levels of dissolved organic molecules, we conducted liquid microjet photoelectron spectroscopy (PES) measurements of the aqueous vertical ionization energies (VIEaq) of aniline (7.49 eV), v ...

Amer Chemical Soc2015

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Functional pi-conjugated molecules are relevant for the preparation of new organic electronic materials with improved performance. However, their synthesis is often rendered difficult by their inherently low solubility, and the permanent attachment of solu ...

Wiley-V C H Verlag Gmbh2015

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Transport of ionic species solvated in electrolytes depends on temperature. This dependence is much stronger in nanofluidics than large scale since the surface charge also varies with temperature. In this work, we introduce a new tool for the modulation of ...

IEEE2015

Impact of MOF topology upon solvent organization, dynamics, and solution phase stability

Wendy Lee Queen, Xiaoning Yang

One large gap in research related to hybrid org./inorg. frameworks pertains to the inability to rationally design materials with targeted structural features and hence properties, a problem that stems from a lack of knowledge of their crystn. processes. Li ...

American Chemical Society2015

Electrochemical Reduction of CO2 Catalyzed by Metal Oxides

Yeonji Oh

A rapidly growing population and industrialization have caused the exploitation of natural resources in keeping with fossil fuels shortage. Due to the combustion of fossil fuels, the concentration of CO2 in the earth's atmosphere, which is a potent greenho ...

EPFL2015

Inorganic salts interact with oxalic acid in submicron particles to form material with low hygroscopicity and volatility

Athanasios Nenes

Volatility and hygroscopicity are two key properties of organic aerosol components, and both are strongly related to chemical identity. While the hygroscopicities of pure salts, di-carboxylic acids (DCA), and DCA salts are known, the hygroscopicity of inte ...

European Geosciences Union2014