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This lecture covers the fundamental concepts of chemical equilibria and reactivity, including the equilibrium constant, the influence of temperature and pressure, excess of a reactant, and the effect of concentration on equilibrium. It also discusses the equilibrium in heterogeneous systems, the influence of ionic equilibria in solutions, and the formation of complexes. The lecture concludes with a detailed explanation of simultaneous equilibria using examples involving the dissolution of ionic compounds. Various exercises are provided to reinforce the understanding of the topics discussed.