Optical and photoemission experiments reveal unexpected spectral signatures of one-dimensional band insulators. In the model compound (NbSe4)(3)I the optical conductivity decays as a power law sigma(1)(omega) similar to omega(-4.25) above a sharp gap edge. Photoemission observes both the valence and a shadow band, produced w by a commensurate superstructure. We identify an optical and photoemission band gap consistent with other measurements but much smaller than the energy scale defined by the dispersion of the band peak in the photoemission spectra.
Andras Kis, Dumitru Dumcenco, Olivier Renault, Dmitrii Unuchek, Hokwon Kim, Nicolas Chevalier
Marco Grioni, Arnaud Magrez, Oleg Yazyev, Daniel Gosalbez Martinez, Helmuth Berger, Alberto Crepaldi, Mauro Fanciulli, Gianmarco Gatti
Majed Chergui, Marco Grioni, Arnaud Magrez, Helmuth Berger, Philippe Bugnon, Alberto Crepaldi, Luca Moreschini, Simon Karl Moser, Gianmarco Gatti, Serhii Polishchuk