Publication

Teaching Enantioselectivity to C-H Bond Functionalizations: Initial Steps of a Rather Long Shot

Nicolai Cramer
2012
Journal paper

Abstract

The direct functionalization of non-activated C-H bonds, especially in an enantioselective manner, requires metal catalysts equipped with ligands with specifically designed properties. Examples for asymmetric C(sp(2))-H and C(sp(3))-H functionalizations using palladium- and rhodium catalysts are shown. This work was rewarded by the 2012 Werner Prize of the Swiss Chemical Society.

Official source

https://infoscience.epfl.ch/record/185282?ln=en

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Teaching Enantioselectivity to C-H Bond Functionalizations: Initial Steps of a Rather Long Shot

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Exploitation of Unconventional Electrophiles in Enantioselective Pd(0)-Catalyzed C-H Functionalizations

Alkynyl Triazenes as Fluoroalkyne Surrogates: Regioselective Access to 4-Fluoro-2-pyridones by a Rh(III)-Catalyzed C–H Activation–Lossen Rearrangement–Wallach Reaction

One-step access to N-enoxyimides by gold-catalysed addition of N-hydroxyimides to terminal alkynes