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Optical rest-frame spectroscopic diagnostics are usually employed to distinguish between star formation and active galactic nucleus (AGN) powered emission. However, this method is biased against dusty sources, hampering a complete census of the AGN population across cosmic epochs. To mitigate this effect, it is crucial to observe at longer wavelengths in the rest-frame near-infrared (near-IR), which is less affected by dust attenuation and can thus provide a better description of the intrinsic properties of galaxies. AGN diagnostics in this regime have not been fully exploited so far, due to the scarcity of near-IR observations of both AGN and star-forming galaxies, especially at redshifts higher than 0.5. Using Cloudy photoionization models, we identified new AGN - star formation diagnostics based on the ratio of bright near-IR emission lines, namely [SIII] 9530 & Aring;, [CI] 9850 & Aring;, [PII] 1.188 mu m, [FeII] 1.257 mu m, and [FeII] 1.64 mu m to Paschen lines (either Pa gamma or Pa beta), providing simple, analytical classification criteria. We applied these diagnostics to a sample of 64 star-forming galaxies and AGN at 0