Are you an EPFL student looking for a semester project?
Work with us on data science and visualisation projects, and deploy your project as an app on top of Graph Search.
Publication
Are you an EPFL student looking for a semester project?
Work with us on data science and visualisation projects, and deploy your project as an app on top of Graph Search.
7-Halo-7-methylnorcaranes (I) and 7,7-dimethylnorcarane (II) are formed via replacement of halogen by Me during the reaction of cyclohexene (III) with carbenes (carbenoids) and MeLi. Thus, III is treated with CHClF2 or CCl2F2 and MeLi to give a mixt. of 7-chloro-7-fluoronorcarane (IV), I, and II. 1,1-Difluoro-2,2-dimethylcyclopropanes (V) are obtained from Me2C:CHMe and Me2C:CH(CH2)2CH(OEt)2. [on SciFinder (R)]
, ,