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Concept
Oxygen sensor
Summary
An oxygen sensor (or lambda sensor, where lambda refers to air–fuel equivalence ratio, usually denoted by λ) or probe or sond, is an electronic device that measures the proportion of oxygen (O2) in the gas or liquid being analysed.
It was developed by Robert Bosch GmbH during the late 1960s under the supervision of Dr. Günter Bauman. The original sensing element is made with a thimble-shaped zirconia ceramic coated on both the exhaust and reference sides with a thin layer of platinum and comes in both heated and unheated forms. The planar-style sensor entered the market in 1990 and significantly reduced the mass of the ceramic sensing element, as well as incorporating the heater within the ceramic structure. This resulted in a sensor that started sooner and responded faster.
The most common application is to measure the exhaust-gas concentration of oxygen for internal combustion engines in automobiles and other vehicles in order to calculate and, if required, dynamically adjust the air-fuel ratio so that catalytic converters can work optimally, and also determine whether the converter is performing properly or not. An oxygen sensor will typically generate up to about 0.9 volt when the fuel mixture is rich and there is little unburned oxygen in the exhaust.
Scientists use oxygen sensors to measure respiration or production of oxygen and use a different approach. Oxygen sensors are used in oxygen analyzers, which find extensive use in medical applications such as anesthesia monitors, respirators and oxygen concentrators.
Divers use oxygen sensors (and often call them ppO2 sensors) to measure the partial pressure of oxygen in their breathing gas. Open circuit scuba divers test the gas before diving as the mixture remains unchanged during the dive and partial pressure changes due to pressure are simply predictable, while mixed gas rebreather divers must monitor the partial pressure of oxygen in the breathing loop throughout the dive, as it changes and must be controlled to stay within acceptable bounds.
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Electro-galvanic oxygen sensor
An electro-galvanic fuel cell is an electrochemical device which consumes a fuel to produce an electrical output by a chemical reaction. One form of electro-galvanic fuel cell based on the oxidation of lead is commonly used to measure the concentration of oxygen gas in underwater diving and medical breathing gases. Electronically monitored or controlled diving rebreather systems, saturation diving systems, and many medical life-support systems use galvanic oxygen sensors in their control circuits to directly monitor oxygen partial pressure during operation.
Zirconium dioxide
Zirconium dioxide (ZrO2) (sometimes known as zirconia, not to be confused with zircon) is a white crystalline oxide of zirconium. Its most naturally occurring form, with a monoclinic crystalline structure, is the mineral baddeleyite. A dopant stabilized cubic structured zirconia, cubic zirconia, is synthesized in various colours for use as a gemstone and a diamond simulant. Zirconia is produced by calcining zirconium compounds, exploiting its high thermostability.