Summary
Charcoal is a lightweight black carbon residue produced by strongly heating wood (or other animal and plant materials) in minimal oxygen to remove all water and volatile constituents. In the traditional version of this pyrolysis process, called charcoal burning, often by forming a charcoal kiln, the heat is supplied by burning part of the starting material itself, with a limited supply of oxygen. The material can also be heated in a closed retort. Modern "charcoal" briquettes used for outdoor cooking may contain many other additives, e.g. coal. This process happens naturally when combustion is incomplete, and is sometimes used in radiocarbon dating. It also happens inadvertently while burning wood, as in a fireplace or wood stove. The visible flame in these is due to combustion of the volatile gases exuded as the wood turns into charcoal. The soot and smoke commonly given off by wood fires result from incomplete combustion of those volatiles. Charcoal burns at a higher temperature than wood, with hardly a visible flame, and releases almost nothing except heat and carbon dioxide. Charcoal burner The production of wood charcoal in locations where there is an abundance of wood dates back to ancient times. It generally begins with piling billets of wood on their ends to form a conical pile. Openings are left at the bottom to admit air, with a central shaft serving as a flue. The whole pile is covered with turf or moistened clay. The firing is begun at the bottom of the flue, and gradually spreads outward and upward. The success of the operation depends upon the rate of the combustion. Under average conditions wood yields about 60% charcoal by volume, or 25% by weight; small-scale production methods often yield only about 50% by volume, while large-scale methods enabled higher yields of about 90% by the 17th century. The operation is so delicate that it was generally left to colliers (professional charcoal burners). They often lived alone in small huts to tend their wood piles.
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