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Troilite is a rare iron sulfide mineral with the simple formula of FeS. It is the iron-rich endmember of the pyrrhotite group. Pyrrhotite has the formula Fe(1-x)S (x = 0 to 0.2) which is iron deficient. As troilite lacks the iron deficiency which gives pyrrhotite its characteristic magnetism, troilite is non-magnetic. Troilite can be found as a native mineral on Earth but is more abundant in meteorites, in particular, those originating from the Moon and Mars. It is among the minerals found in samples of the meteorite that struck Russia in Chelyabinsk on February 15th, 2013. Uniform presence of troilite on the Moon and possibly on Mars has been confirmed by the Apollo, Viking and Phobos space probes. The relative intensities of isotopes of sulfur are rather constant in meteorites as compared to the Earth minerals, and therefore troilite from Canyon Diablo meteorite is chosen as the international sulfur isotope ratio standard, the Canyon Diablo Troilite (CDT). Troilite has hexagonal structure (Pearson symbol hP24, Space group P-62c No 190). Its unit cell is approximately a combination of two vertically stacked basic NiAs-type cells of pyrrhotite, where the top cell is diagonally shifted. For this reason, troilite is sometimes called pyrrhotite-2C. A meteorite fall was observed in 1766 at Albareto, Modena, Italy. Samples were collected and studied by Domenico Troili who described the iron sulfide inclusions in the meteorite. These iron sulfides were long considered to be pyrite (i.e., ). In 1862, German mineralogist Gustav Rose analyzed the material and recognized it as stoichiometric 1:1 FeS and gave it the name troilite in recognition of the work of Domenico Troili. Troilite has been reported from a variety of meteorites occurring with daubréelite, chromite, sphalerite, graphite, and a variety of phosphate and silicate minerals. It has also been reported from serpentinite in the Alta mine, Del Norte County, California, and in layered igneous intrusions in Western Australia, the Ilimaussaq intrusion of southern Greenland, the Bushveld Complex in South Africa and at Nordfjellmark, Norway.

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Pyrite Oxidation: Metal Release MOOC: Water quality and the biogeochemical engine

Explores pyrite formation, oxidation pathways, metal release, bacterial impact, nitrate decontamination, and acid rain production.

Oxidation of pyrite (FeS2) and troilite (FeS) impurities in kaolinitic clays after calcination

Karen Scrivener, Franco Alberto Zunino Sommariva

Valorisation of locally available clays for producing blended cements is crucial for a widespread adoption of sustainable binders incorporating these materials. In some places, clays can be intermixed with small amounts of iron sulfides, which could eventu ...

SPRINGER2022

Physical and microstructural aspects of iron sulfide degradation in concrete

Karen Scrivener, Emmanuel Gallucci

The microstructural aspects of iron sulfide degradation in dam concrete were investigated by scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS) in both dam concrete samples and laboratory concrete. The results show that iron sulfid ...

2011

Medium resolution X-Ray Computed Tomography of hollow cylindrical samples of Boom Clay

Laurent Gastaldo, Vincent Labiouse, Shuang You, Laura Vigne

Laboratory experiments carried out at the LMR-EPFL on thick-walled hollow cylindrical samples aim at modelling at small-scale conditions similar to those that will be experienced by host rocks around disposal galleries for heat emitting radioactive waste. ...

CRC Press/Balkema2010