The oceanic carbon cycle (or marine carbon cycle) is composed of processes that exchange carbon between various pools within the ocean as well as between the atmosphere, Earth interior, and the seafloor. The carbon cycle is a result of many interacting forces across multiple time and space scales that circulates carbon around the planet, ensuring that carbon is available globally. The Oceanic carbon cycle is a central process to the global carbon cycle and contains both inorganic carbon (carbon not associated with a living thing, such as carbon dioxide) and organic carbon (carbon that is, or has been, incorporated into a living thing). Part of the marine carbon cycle transforms carbon between non-living and living matter.
Three main processes (or pumps) that make up the marine carbon cycle bring atmospheric carbon dioxide (CO2) into the ocean interior and distribute it through the oceans. These three pumps are: (1) the solubility pump, (2) the carbonate pump, and (3) the biological pump. The total active pool of carbon at the Earth's surface for durations of less than 10,000 years is roughly 40,000 gigatons C (Gt C, a gigaton is one billion tons, or the weight of approximately 6 million blue whales), and about 95% (~38,000 Gt C) is stored in the ocean, mostly as dissolved inorganic carbon. The speciation of dissolved inorganic carbon in the marine carbon cycle is a primary controller of acid-base chemistry in the oceans.
Earth's plants and algae (primary producers) are responsible for the largest annual carbon fluxes. Although the amount of carbon stored in marine biota (~3 Gt C) is very small compared with terrestrial vegetation (~610 GtC), the amount of carbon exchanged (the flux) by these groups is nearly equal – about 50 GtC each. Marine organisms link the carbon and oxygen cycles through processes such as photosynthesis. The marine carbon cycle is also biologically tied to the nitrogen and phosphorus cycles by a near-constant stoichiometric ratio C:N:P of 106:16:1, also known as the Redfield Ketchum Richards (RKR) ratio, which states that organisms tend to take up nitrogen and phosphorus incorporating new organic carbon.
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The Redfield ratio or Redfield stoichiometry is the consistent atomic ratio of carbon, nitrogen and phosphorus found in marine phytoplankton and throughout the deep oceans. The term is named for American oceanographer Alfred C. Redfield who in 1934 first described the relatively consistent ratio of nutrients in marine biomass samples collected across several voyages on board the research vessel Atlantis, and empirically found the ratio to be C:N:P = 106:16:1.
Particulate inorganic carbon (PIC) can be contrasted with dissolved inorganic carbon (DIC), the other form of inorganic carbon found in the ocean. These distinctions are important in chemical oceanography. Particulate inorganic carbon is sometimes called suspended inorganic carbon. In operational terms, it is defined as the inorganic carbon in particulate form that is too large to pass through the filter used to separate dissolved inorganic carbon. Most PIC is calcium carbonate, CaCO3, particularly in the form of calcite, but also in the form of aragonite.
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