Chemical reactors and reactions

Related publications (137)

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Electrocatalytic conversion of CO2 to valuable chemicals is a highly promising route to close the carbon cycle. Herein, Zn catalysts derived from electrochemical reconstruction of ZnO materials are presented as efficient CO2-to-CO catalysts. We found that ...

2020

We compare two reactor setups commonly used to make operando measurements of catalyst behavior using X-rays in terms of the degree to which they may be considered to yield radial and axial isothermality. We use axial and radial Cu K-edge XANES mapping of c ...

ROYAL SOC CHEMISTRY2019

Dynamic Optimization of Reaction Systems via Exact Parsimonious Input Parameterization

Dominique Bonvin, Diogo Filipe Mateus Rodrigues

This paper discusses the use of parsimonious input parameterization for the dynamic optimization of reaction systems. This parameterization is able to represent the optimal inputs with only a few parameters. In the context of batch, semibatch, and continuo ...

AMER CHEMICAL SOC2019

Cascade catalytic processes perform multi-step chemical transformations without isolating the intermediates. Here, we demonstrate a sequential cascade pathway to convert CO2 to C2+ hydrocarbons and oxygenates in a two-step electrocatalytic process using CO ...

2019

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Ice-covered waterbodies are far from being quiescent systems. In this paper, we investigate ice-covered freshwater basins heated by solar radiation that penetrates across waters with temperatures below or near the temperature of maximum density. In this sc ...

2018

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A proof-of-concept prototype of a medium-scale heterogeneous catalytic reactor for continuous production of hydrogen through formic acid (FA) dehydrogenation has been developed. A commercial proton exchange membrane (PEM) fuel cell (FC) fed with the result ...

2018

Modifier adaptation with guaranteed feasibility in the presence of gradient uncertainty

Dominique Bonvin, Timm Faulwasser, Alejandro Gabriel Marchetti, Martand Singhal

In the context of real-time optimization, modifier-adaptation schemes use estimates of the plant gradients to achieve plant optimality despite plant-model mismatch. Plant feasibility is guaranteed upon convergence, but not at the successive operating point ...

Pergamon-Elsevier Science Ltd2017

Data Reconciliation for Reaction Systems Using Extents and Shape Constraints

Dominique Bonvin, Julien Léo Billeter, Sriniketh Srinivasan

Concentrations measured during the course of reactions are typically corrupted by random noise. Data reconciliation techniques improve the accuracy of measurements by using redundancies in the material and energy balances expressed as relationships between ...

Elsevier2017

Chemoselective three-phase hydrogenation of an Ombrabulin nitro-stilbene intermediate in a continuous-flow mobile platform

Lioubov Kiwi, Charline Berguerand

The chemoselective three-phase hydrogenation of an Ombrabulinintermediate based on a nitro-stilbene framework was used as a case study for the formation of the primary amine without affecting the double bond. Two catalysts were tested: Pt nanoparticles sup ...

Elsevier Science Sa2017

Reactor Dynamics Investigation Based On Calorimetric Data

Thierry Meyer, Francis Stoessel, Michal Dabros, Charles Ibrahim Guinand

A simple and general procedure has been developed to determine the thermal behaviour of a reactor based on heat balance, PID temperature control, and jacket behaviour. Using only temperature heating/cooling ramps followed by isothermal stages, such a proce ...

Wiley-Blackwell2017