The constant urge to construct new molecules in an economical and sustainable fashion led to the development of numerous metal-catalyzed transformations. Organocatalysts consisting of abundant and more sustainable elements offer an elegant solution to over ...
A promising approach for the production of highly efficient and stable hybrid perovskite solar cells is employing mixed-ion materials. Remarkable performances have been reached by materials comprising a stabilized mixture of methylammonium (MA(+)) and form ...
2021
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In this issue of Chem, Dong and colleagues show that an engineered mixed carboxylate carbonate anhydride serves as an electrophilic trap in palladium/norbornene-catalyzed double functionalization of aryl iodides, enabling the introduction of the synthetica ...
Cell Press2016
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Chemical modification such as intercalation or doping of novel materials is of great importance for exploratory material science and applications in various fields of physics and chemistry. Herein, the systematic intercalation of chemically exfoliated few- ...
Here we introduce a new solvent-free preparation method for hybrid metal halide perovskites involving the direct reaction of metallic lead with polyiodide melts. We discovered new reactive polyiodide melts (RPMs) that can be prepared simply by adding eleme ...
This work report, for the first time, the co-doping of mesoporous TiO2 with Cd2+ and La3+ cations for improved performance of dye-sensitized solar cells (DSSCs). Cd2+ ions modify the TiO2 lattice interstitially and lower the band gap enabling better electr ...
Elsevier2017
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Herein, we report the synthesis and characterization of a series of terminal uranium(IV) hydrosulfido and sulfido complexes, supported by the hexadentate, tacn-based ligand framework (Ad,MeArO)3tacn3– (= trianion of 1,4,7-tris(3-adamantyl-5-methyl-2-hydrox ...
Royal Soc Chemistry2016
Iodine is a naturally-occurring halogen in natural waters generally present in concentrations between 0.5 and 100 mu g L-1. During oxidative drinking water treatment, iodine-containing disinfection by-products (I-DBPs) can be formed. The formation of I-DBP ...
Early diagnosis of acute cartilage injuries enables monitoring of disease progression and improved treatment option planning to prevent post-traumatic osteoarthritis. In contrast-enhanced computed tomography (CECT), the changes in cationic agent diffusion ...
The kinetics for the reactions of hypoiodous acid (HOI) with various phenols (phenol, 4-nitrophenol, 4-hydroxybenzoic acid), 3-oxopentanedioic acid (3-OPA) and flavone were investigated in the pH range of 6.0-11.0. The apparent second order rate constants ...