Molecular symmetryIn chemistry, molecular symmetry describes the symmetry present in molecules and the classification of these molecules according to their symmetry. Molecular symmetry is a fundamental concept in chemistry, as it can be used to predict or explain many of a molecule's chemical properties, such as whether or not it has a dipole moment, as well as its allowed spectroscopic transitions. To do this it is necessary to use group theory. This involves classifying the states of the molecule using the irreducible representations from the character table of the symmetry group of the molecule.
Coxeter notationIn geometry, Coxeter notation (also Coxeter symbol) is a system of classifying symmetry groups, describing the angles between fundamental reflections of a Coxeter group in a bracketed notation expressing the structure of a Coxeter-Dynkin diagram, with modifiers to indicate certain subgroups. The notation is named after H. S. M. Coxeter, and has been more comprehensively defined by Norman Johnson. For Coxeter groups, defined by pure reflections, there is a direct correspondence between the bracket notation and Coxeter-Dynkin diagram.
Symmetry (geometry)In geometry, an object has symmetry if there is an operation or transformation (such as translation, scaling, rotation or reflection) that maps the figure/object onto itself (i.e., the object has an invariance under the transform). Thus, a symmetry can be thought of as an immunity to change. For instance, a circle rotated about its center will have the same shape and size as the original circle, as all points before and after the transform would be indistinguishable.
Bravais latticeIn geometry and crystallography, a Bravais lattice, named after , is an infinite array of discrete points generated by a set of discrete translation operations described in three dimensional space by where the ni are any integers, and ai are primitive translation vectors, or primitive vectors, which lie in different directions (not necessarily mutually perpendicular) and span the lattice. The choice of primitive vectors for a given Bravais lattice is not unique.
Symmetry operationIn group theory, geometry, representation theory and molecular geometry, a symmetry operation is a geometric transformation of an object that leaves the object looking the same after it has been carried out. For example, as transformations of an object in space, rotations, reflections and inversions are all symmetry operations. Such symmetry operations are performed with respect to symmetry elements (for example, a point, line or plane).
Uniform 4-polytopeIn geometry, a uniform 4-polytope (or uniform polychoron) is a 4-dimensional polytope which is vertex-transitive and whose cells are uniform polyhedra, and faces are regular polygons. There are 47 non-prismatic convex uniform 4-polytopes. There are two infinite sets of convex prismatic forms, along with 17 cases arising as prisms of the convex uniform polyhedra. There are also an unknown number of non-convex star forms.
Point groups in two dimensionsIn geometry, a two-dimensional point group or rosette group is a group of geometric symmetries (isometries) that keep at least one point fixed in a plane. Every such group is a subgroup of the orthogonal group O(2), including O(2) itself. Its elements are rotations and reflections, and every such group containing only rotations is a subgroup of the special orthogonal group SO(2), including SO(2) itself. That group is isomorphic to R/Z and the first unitary group, U(1), a group also known as the circle group.
Euclidean plane isometryIn geometry, a Euclidean plane isometry is an isometry of the Euclidean plane, or more informally, a way of transforming the plane that preserves geometrical properties such as length. There are four types: translations, rotations, reflections, and glide reflections (see below under ). The set of Euclidean plane isometries forms a group under composition: the Euclidean group in two dimensions. It is generated by reflections in lines, and every element of the Euclidean group is the composite of at most three distinct reflections.
Square latticeIn mathematics, the square lattice is a type of lattice in a two-dimensional Euclidean space. It is the two-dimensional version of the integer lattice, denoted as \mathbb{Z}^2. It is one of the five types of two-dimensional lattices as classified by their symmetry groups; its symmetry group in IUC notation as p4m, Coxeter notation as [4,4], and orbifold notation as *442. Two orientations of an image of the lattice are by far the most common.
Point groups in four dimensionsIn geometry, a point group in four dimensions is an isometry group in four dimensions that leaves the origin fixed, or correspondingly, an isometry group of a 3-sphere. 1889 Édouard Goursat, Sur les substitutions orthogonales et les divisions régulières de l'espace, Annales Scientifiques de l'École Normale Supérieure, Sér. 3, 6, (pp. 9–102, pp. 80–81 tetrahedra), Goursat tetrahedron 1951, A. C. Hurley, Finite rotation groups and crystal classes in four dimensions, Proceedings of the Cambridge Philosophical Society, vol.