Cordierite (mineralogy) or iolite (gemology) is a magnesium iron aluminium cyclosilicate. Iron is almost always present and a solid solution exists between Mg-rich cordierite and Fe-rich sekaninaite with a series formula: to . A high-temperature polymorph exists, indialite, which is isostructural with beryl and has a random distribution of Al in the rings.
Cordierite, which was discovered in 1813, in specimens from Níjar, Almería, Spain, is named after the French geologist Louis Cordier (1777–1861).
Cordierite typically occurs in contact or regional metamorphism of pelitic rocks. It is especially common in hornfels produced by contact metamorphism of pelitic rocks. Two common metamorphic mineral assemblages include sillimanite-cordierite-spinel and cordierite-spinel-plagioclase-orthopyroxene. Other associated minerals include garnet (cordierite-garnet-sillimanite gneisses) and anthophyllite. Cordierite also occurs in some granites, pegmatites, and norites in gabbroic magmas. Alteration products include mica, chlorite, and talc. Cordierite occurs, for example, in the granite contact zone at Geevor Tin Mine in Cornwall.
Catalytic converters are commonly made from ceramics containing a large proportion of synthetic cordierite. The manufacturing process deliberately aligns the cordierite crystals to make use of the very low thermal expansion along one axis. This prevents thermal shock cracking from taking place when the catalytic converter is used.
As the transparent variety iolite, it is often used as a gemstone. The name "iolite" comes from the Greek word for violet. Another old name is dichroite, a Greek word meaning "two-colored rock", a reference to cordierite's strong pleochroism. It has also been called "water-sapphire" and "Vikings' Compass" because of its usefulness in determining the direction of the sun on overcast days, the Vikings having used it for this purpose. This works by determining the direction of polarization of the sky overhead.
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The chlorites are the group of phyllosilicate minerals common in low-grade metamorphic rocks and in altered igneous rocks. Greenschist, formed by metamorphism of basalt or other low-silica volcanic rock, typically contains significant amounts of chlorite. Chlorite minerals show a wide variety of compositions, in which magnesium, iron, aluminium, and silicon substitute for each other in the crystal structure. A complete solid solution series exists between the two most common end members, magnesium-rich clinochlore and iron-rich chamosite.
Beryl (ˈbɛrəl ) is a mineral composed of beryllium aluminium silicate with the chemical formula Be3Al2Si6O18. Well-known varieties of beryl include emerald and aquamarine. Naturally occurring, hexagonal crystals of beryl can be up to several meters in size, but terminated crystals are relatively rare. Pure beryl is colorless, but it is frequently tinted by impurities; possible colors are green, blue, yellow, pink, and red (the rarest). It is an ore source of beryllium.
Metamorphism is the transformation of existing rock (the protolith) to rock with a different mineral composition or texture. Metamorphism takes place at temperatures in excess of , and often also at elevated pressure or in the presence of chemically active fluids, but the rock remains mostly solid during the transformation. Metamorphism is distinct from weathering or diagenesis, which are changes that take place at or just beneath Earth's surface. Various forms of metamorphism exist, including regional, contact, hydrothermal, shock, and dynamic metamorphism.
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