Concept
Charge-transfer complex
Related publications (69)
The Mn(VII)-H2O2 oxidation process: Abatement of electron-deficient N-containing organic compounds
Chemical oxidants applied in water treatment are electrophiles, which preferentially attack sites with higher electron density. This typically results in less efficient oxidative abatement of organic compounds with electronwithdrawing substituents. In this ...
Lausanne2024Synthesis and investigation of the thermal proper- ties of [Co(N H-3)(6)] [Co(C2O4)(3)]center dot 3H(2)O and [Ir(NH3)(6)][Ir(C2O4)(3)]
The complexes [Co (NH3)(6)][Ir (C2O4)(3)] and [Ir(NH3)(6)][Co (C2O4)(3)center dot H2O have previously been synthesized and their thermal properties studied. The [Ir(NH3)(6)][Ir(C2O4)(3)] and [Co(NH3)(6)][Co(C2O4)(3)]center dot 3H(2)O complexes considered h ...
INT UNION CRYSTALLOGRAPHY2022How Forward-Scattering Snow and Terrain Change the Alpine Radiation Balance With Application to Solar Panels
Rough terrain in mid- and high latitudes is often covered with highly reflective snow, giving rise to a very complex transfer of incident sunlight. In order to simplify the radiative transfer in weather and climate models, snow is generally treated as an i ...
AMER GEOPHYSICAL UNION2021Schiff base ligands derived from 1,2-bis(2 '-nitro-/amino-phenoxy)-3-R-benzene and 2-hydroxy-1-naphthaldehyde and their Cu/Zn(II) complexes: synthesis, characterization, X-ray structures and computational studies
1,2-Bis(2'-nitrophenoxy)-3-R-benzenes {R = H (1), CH3 (2) and OCH3 (3)} have been prepared from the S-N-Ar reaction between 1-fluoro-2-nitrobenzene and 3-R-catechol (aromatic diol), and are then reduced to the corresponding diamines 1,2-bis(2'-aminophenoxy ...
ROYAL SOC CHEMISTRY2021Charge transfer dynamics in Ar+ + CO
Differential cross sections for the charge transfer reaction between Ar(+)and CO have been measured using three-dimensional velocity map imaging in a crossed beam setup at the two relative collision energies 0.55 and 0.74 eV. We find dominant forward scatt ...
2020Effects of composition and pressure on electronic states of iron in bridgmanite
Arnaud Magrez, Philippe Gillet, Susannah McGregor Dorfman
Electronic states of iron in the lower mantle's dominant mineral, (Mg,Fe,Al)(Fe,Al,Si)O-3 bridgmanite, control physical properties of the mantle including density, elasticity, and electrical and thermal conductivity. However, the determination of electroni ...
MINERALOGICAL SOC AMER2020Microscopic Picture of the Solvent Reorganization During Electron Transfer to Flavin in Water
The redox potential of molecular species is largely modulated by its molecular environment so that a change of the environment will lead to a different redox potential. However, a detailed molecular picture of reorganization of the environment upon reducti ...
AMER CHEMICAL SOC2019Charge-transfer and impulsive electronic-to-vibrational energy conversion in ferricyanide: ultrafast photoelectron and transient infrared studies'
Majed Chergui, Christopher Alexander Arrell, José Javier Pancracio Ojeda Andara, Luca Longetti
The photophysics of ferricyanide in H2O, D2O and ethylene glycol was studied upon excitation of ligand-to-metal charge transfer (LMCT) transitions by combining ultrafast photoelectron spectroscopy (PES) of liquids and transient vibrational spectroscopy. Up ...
Royal Society of Chemistry2017Quantifying Electronic Phenomena in Organic Chromophores
Challenging ground and excited state problems in the chemistry of common organic chromophores are investigated with state-of-the-art quantum chemical methods. We present a comprehensive excited state molecular dynamics analysis of (a) fundamental building ...
EPFL2017Assemblies of gold nanoparticles at liquid-liquid interfaces
The interface between two immiscible liquids, i.e. oil and water, is an extremely attractive scaffold to self-assemble nanoparticles (NP) in arranged films. The liquid-liquid interfaces (LLIs) are defect-free and pristine by the nature, they are transparen ...
EPFL2017