The aim of this thesis has been to assess the potential of branched polymers as novel exfoliants for layered silicates and their application in polyurethanes. Three different types of –OH functional branched polymers have been studied: dendrimers, hyperbra ...
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C60 fullerene reacted with phosphorus at high temperatures to graphitic materials with strongly differing properties. Several spectroscopic investigations as Raman, ESR, XPS and 31P-NMR as well as TEM and ESEM have shown that the structural order of the mo ...
We determine from first principles the finite-temperature properties-linewidths, line shifts, and lifetimes-of the key vibrational modes that dominate inelastic losses in graphitic materials. In graphite, the phonon linewidth of the Raman-active E-2g mode ...
The processing and application of graphite powder-based sacrificial layer for fabrication of microfluidic structures in LTCC is described. Such layers are produced as pastes, which are screen-printed in LTCC sheets to avoid sagging, by supporting closed, t ...
A review with refs. concerning electrochem. oxidn. of orgs. in aq. media on iridium oxide and synthetic diamond based electrodes is presented. Effect of nature of electrode material influence on selectivity and efficiency of this process is considered. The ...
Aluminum is produced by the electrolytic reduction of alumina dissolved in molten cryolite. This process requires carbon anodes which are consumed during the electrolysis. The anodes contribute roughly with 15% to the total aluminum production cost. If the ...
This paper deals with the electrochem. reactivity of B doped diamond (BDD) electrodes. A comparative study was carried out to show the influence of the presence of graphitic micro-domains upon the surface of these films. Those graphitic domains are sometim ...
The methoxylation of p-tert-butyltoluene (TBT) in CH3OH-H2SO4-H2O soln. has been investigated on graphite and boron-doped diamond (BDD) anodes. Different reaction intermediates have been found on BDD and graphite. In fact BDD electrodes favor the formation ...
Electrodeposition on Highly Oriented Pyrolytic Graphite (HOPG) steps has been proven to be an easy method for the preparation of metal (Pd, Cu, Ag etc) and metal oxide or sulfide (MoO2, MnO2, MoS2) nanowires in recent years. These wires can be transferred ...
Electrodeposition on Highly Oriented Pyrolytic Graphite (HOPG) steps has been proven to be an easy method for the preparation of metal (Pd, Cu, Ag etc) and metal oxide or sulfide (MoO2, MnO2, MoS2) nanowires in recent years. These wires can be transferred ...