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Me3CLi metalated LiOCH2C:CCH2OTHP (THP = tetrahydro-2-pyranyl) quant. to LiOCH2CLi:C:CHOTHP which was treated with MeOH, Me(CH2)5I, or PhCH2Cl to give LiOCH2CR:C:CHOTHP [I; R = H, (CH2)5Me, CH2Ph]. Treating I with Me3CLi gave LiOCH2CR:C:CLiOTHP [R = (CH2)5 ...
Short-wavelength irradn. of Ph3P+C-Me2 gave C6H6 and a resinous compd. Long-wavelength irradn. of Ph3P+C-Me2 gave mainly Ph3P and Me2C:CMe2 with some Me2CHCHMe2, MeCH:CH2, and, with Me2CHCHMe2 as solvent, traces of (Me2CH)2CMe2 and Me2CHCHMeCH2CHMe2. the r ...
Context. Observations show that small-scale vortical plasma motions are ubiquitous in the quiet solar atmosphere. They have received increasing attention in recent years because they are a viable candidate mechanism for the heating of the outer solar atmos ...
Plasma exhaust has been identified as a major challenge towards the realisation of magnetic confinement fusion. To mitigate the risk that the single null divertor (SND) with a high radiation fraction in the scrape-of-layer (SOL) adopted for ITER will not e ...
We present the results of a search for high-energy muon neutrinos with the IceCube detector in coincidence with the Crab Nebula flare reported on 2010 September by various experiments. Due to the unusual flaring state of the otherwise steady source we perf ...
Purified LiAlH4 reacts with fluorinated alcs. HORF to give LiAl(ORF)4 (RF = -CH(CF3)2, 2a; -CMe(CF3)2, 2b; -C(CF3)3, 2c) in 77-90% yield. The crude Li aluminates LiAl(ORF)4 react metathetically with AgF to give the silver aluminates AgAl(ORF)4 (RF = -CH(CF ...
Coronal Mass ejections (CMEs) are enormous eruptions of magnetized plasma expelled from the Sun into the interplanetary space, over the course of hours to days. They can create major disturbances in the interplanetary medium and trigger severe magnetic sto ...