Concept
Aluminium chloride
Related publications (90)
Nanogels with Metal‐Organic Cages as Functional Crosslinks
A dinuclear metal-organic cage with four acrylate side chains was prepared by self-assembly. Precipitation polymerization of the cage with N-isopropylacrylamide yielded a thermoresponsive nanogel. The host properties of the cage were retained within the ge ...
2024Well-Defined Ti Surface Sites in Ziegler-Natta Pre-Catalysts from 47/49Ti Solid-State Nuclear Magnetic Resonance Spectroscopy
Treatment of Ziegler-Natta (ZN) catalysts with BCl3 improves their activity by increasing the number of active sites. Here we show how Ti-47/49 solid-state nuclear magnetic resonance (NMR) spectroscopy enables us to understand the electronic structure of t ...
Washington2024Synthetic Receptors with Micromolar Affinity for Chloride in Water
Kay Severin, Farzaneh Fadaei Tirani, Damien Wen Chen, Cesare Berton, Sylvain Alexandre Marie Sudan
A water-soluble coordination cage was obtained by reaction of Pd(NO3)2 with a 1,3-di(pyridin-3-yl)benzene ligand featuring a short PEG chain. The cavity of the metal-organic cage contains one nitrate anion, which is readily replaced by chloride. The appare ...
Wiley2023The spatial distribution of cobalt phthalocyanine and copper nanocubes controls the selectivity towards C-2 products in tandem electrocatalytic CO2 reduction
Raffaella Buonsanti, Anna Loiudice, Min Wang, Valery Okatenko
The coupling of CO-generating molecular catalysts with copper electrodes in tandem schemes is a promising strategy to boost the formation of multi-carbon products in the electrocatalytic reduction of CO2. While the spatial distribution of the two component ...
ROYAL SOC CHEMISTRY2023Potent and selective anticancer activity of half-sandwich ruthenium and osmium complexes with modified curcuminoid ligands
Paul Joseph Dyson, Mouna Hadiji
We have recently reported a series of half-sandwich ruthenium(ii) complexes with curcuminoid ligands showing excellent cytotoxic activities (particularly ionic derivatives containing PTA (PTA = 1,3,5-triaza-7-phosphaadamantane). In the present study, new m ...
ROYAL SOC CHEMISTRY2022Understanding of the factors slowing down metakaolin reaction in limestone calcined clay cement (LC3) at late ages
Karen Scrivener, Paul Bowen, Yosra Briki, Mohsen Ben Haha, François Henri Avet
Factors which could explain the slowing down of the metakaolin reaction in LC3 blends are investigated. Portlandite availability and the presence of aluminium ions in the pore solution are shown not to be limiting factors. Hydrates can only precipitate in ...
PERGAMON-ELSEVIER SCIENCE LTD2021Bias-Adaptable CO2-to-CO Conversion via Tuning the Binding of Competing Intermediates
Yelin Hu, Jun Li, Shilong Wang, Han Zhang, An Zhang
CO2 electroreduction powered by renewable electricity represents a promising method to enclose anthropogenic carbon cycle. Current catalysts display high selectivity toward the desired product only over a narrow potential window due primarily to unoptimize ...
AMER CHEMICAL SOC2021Interfacial Effect between Aluminum-Based Complex Hydrides and Nickel-Containing Porous Carbon Sheets
Andreas Züttel, Emad Oveisi, Heena Yang, Mo Li, Youngdon Ko
Supported aluminum-based complex hydrides (alanates) were investigated in view of their interaction at the interface. Nickel-containing porous carbon sheets (Ni-PCSs) were combined with various alanates, resulting in a decrease of the decomposition tempera ...
AMER CHEMICAL SOC2020A polymeric ionic liquid catalyst for the N-formylation and N-methylation of amines using CO2/PhSiH3
Paul Joseph Dyson, Andreas Züttel, Zhaofu Fei, Serhii Shyshkanov, Kyriakos Stylianou, Arunraj Chidambaram, Aswin Gopakumar, Dmitry Vasilyev
We describe a polymeric ionic liquid (PIL) derived from trimethyl(p-vinylbenzyl)ammonium chloride ([VBTAm]Cl) that efficiently catalyzes the N-formylation of amines employing CO2 and PhSiH3 at room temperature with low catalyst loadings in near-quantitativ ...
2020Principal Descriptors of Ionic Liquid Co-catalysts for the Electrochemical Reduction of CO2
Mohammad Khaja Nazeeruddin, Paul Joseph Dyson, Serhii Shyshkanov, Dmitry Vasilyev, Erfan Shirzadi
Electrochemical reduction of carbon dioxide (CO2RR) is promoted by ionic liquid (IL) co-catalysts, and several mechanisms have been proposed to explain their role. Due to the complexity of the CO2RR and the limited number of active IL co-catalysts, a conse ...
AMER CHEMICAL SOC2020