Verdigris ˈv3rdɪɡriː(s) is a common name for any of a variety of poisonous copper salts of acetic acid, which range in colour from green to a bluish-green depending on their chemical composition. Verdigris has been used for artistic purposes from antiquity until the late 20th century, including in easel painting, polychromatic sculptures, and illumination of maps. Verdigris was a common ingredient in colouring agents and pharmaceutical preparations. A leading production site in Montpellier, France was run by women for centuries, providing an important source of female employment. Until the 19th century, verdigris was the most vibrant green pigment available and was frequently used in paintings. However, due to its instability, its popularity declined as other green pigments became readily available. The instability of its appearance stems from its hydration level and basicity, which changes as the pigment interacts with other materials over time.
The name verdigris comes from the Middle English vertegrez, from the Old French verte grez. According to one view, it comes from vert d'aigre, "green [made by action] of vinegar". The modern French writing of this word is vert-de-gris ("green of grey"), sounding like the older name verdet gris ("grey greenish"), itself a deformation of verte grez. It was used as a pigment in paintings and other art objects (as green color), mostly imported from Greece, and hence it is more usually given another etymology as vert-de-Grèce ("green of Greece").
The industry was long dominated by the women of Montpelier, France, which had the ideal climate to produce pulverised verdigris. It was a profitable business, and 80% of production was sold abroad through certified female brokers. At the height of its popularity, in the 1710s, the government had to enforce inspection systems to address growing fraudulent practices. By the 20th century, the production of verdigris had moved away from Montpellier and more cost-efficient methods of producing green pigments sent the industry into decline after WWI.
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Acetic acid əˈsiːtᵻk, systematically named ethanoic acid ˌɛθəˈnoʊᵻk, is an acidic, colourless liquid and organic compound with the chemical formula (also written as , , or ). Vinegar is at least 4% acetic acid by volume, making acetic acid the main component of vinegar apart from water and other trace elements. Acetic acid is the second simplest carboxylic acid (after formic acid). It is an important chemical reagent and industrial chemical, used primarily in the production of cellulose acetate for photographic film, polyvinyl acetate for wood glue, and synthetic fibres and fabrics.
Patina (pəˈtiːnə or ˈpætᵻnə) is a thin layer that variously forms on the surface of copper, brass, bronze and similar metals and metal alloys (tarnish produced by oxidation or other chemical processes) or certain stones and wooden furniture (sheen produced by age, wear, and polishing), or any similar acquired change of a surface through age and exposure. Additionally, the term is used to describe the aging of high-quality leather. The patinas on leather goods are unique to the type of leather, frequency of use, and exposure.
Lead-tin yellow is a yellow pigment, of historical importance in oil painting, sometimes called the "Yellow of the Old Masters" because of the frequency with which it was used by those famous painters. The name lead-tin yellow is a modern label. During the thirteenth to eighteenth centuries when it was in widest use, it was known by a variety of names. In Italy, it was giallorino or giallolino. In other countries of Europe, it was massicot, genuli (Spanish), Plygal (German), general (English) or mechim (Portuguese).
Electrochemical acetoxylation has been widely investigated about 40 years ago. However, there are only a limited number of studies in non-aqueous electrolytes, mainly because of difficulties related with the extremely low electrical conductivity of organic ...
Equilibrium geometries and electronic properties of neutral Cu-n (n = 2, 3, 4, 6, 8, 10) clusters are determined via first principles calculations which treat s and d electrons on an equal footing. Overall, we find ground state and local minimum structures ...