Concept

Rate-determining step

Related publications (393)

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EPFL2021

Studies of cold chemistry in crossed and merged neutral beams

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In this thesis we present the design of two setups to study low-energy collisions between neutral species: an electron velocity map imaging for chemi-ionisation reactions and a merged electrostatic guide for polar molecules scattering. In the past few year ...

EPFL2021

Asymmetric Elimination Reaction on Chiral Metal Surfaces

Harald Brune, Roland Widmer, Martina Danese, Daniele Passerone, Samuel Thomas Stolz

The production of enantiopure materials and molecules is of uttermost relevance in research and industry in numerous contexts, ranging from nonlinear optics to asymmetric synthesis. In the context of the latter, dehalogenation, which is an essential reacti ...

WILEY-V C H VERLAG GMBH2021

Study of He/Ne+Ar, Kr, N2, H2, D2 Chemi-Ionization Reactions by Electron Velocity-Map Imaging

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The chemi-ionization of Ar, Kr, N2, H2, and D2 by Ne(3P2) and of Ar, Kr, and N2 by He(3S1) was studied by electron velocity map imaging (e-VMI) in a crossed molecular beam experiment. A curved magnetic hexapole was used to state-select the metastable speci ...

2021

Gold-in-copper at low *CO coverage enables efficient electromethanation of CO2

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The renewable-electricity-powered CO2 electroreduction reaction provides a promising means to store intermittent renewable energy in the form of valuable chemicals and dispatchable fuels. Renewable methane produced using CO2 electroreduction attracts inter ...

NATURE RESEARCH2021

Effects of impurities and local behavior characterization using active thermography on solid oxide electrolysis cells

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Ambitious policies are needed from every country to drastically curtail the anthropogenic emission of greenhouse gases responsible for the on-going modification of the earth's climate. A quick transition towards a society fully based on renewable materials ...

EPFL2021

Dissipation-driven selection of states in non-equilibrium chemical networks

Paolo De Los Rios, Daniel Maria Busiello, Shiling Liang, Francesco Piazza

Life has most likely originated as a consequence of processes taking place in non-equilibrium conditions (e.g. in the proximity of deep-sea thermal vents) selecting states of matter that would have been otherwise unfavorable at equilibrium. Here we present ...

2021

Reduction of PdO/Al2O3 in Liquid Cyclohexane Followed In Situ by ATR-IR, High-Energy XRD, and XAS

Davide Ferri

Supported Pd-based catalysts used in heterogeneously catalyzed liquid phase processes often undergo an activation step through reduction of the oxide phase or of the oxidic passivation layer prior to reaction. An oxidized Pd/Al2O3 catalyst was reduced by u ...

AMER CHEMICAL SOC2021

Dosimetry modeling and experimental validation for the PETALE program in the CROCUS reactor

Andreas Pautz, Vincent Pierre Lamirand, Pavel Frajtag, Axel Guy Marie Laureau

The PETALE experimental program in the CROCUS reactor intends to provide integral measurements on reactivity worth and dosimetry measurement to constrain nuclear data relative to stainless steel heavy reflectors. The experimental setup consists in eight su ...

2021

Atomic Level Insights of Non-Noble Metal Catalysts for the Oxygen Evolution Reaction

Lichen Bai

The conversion of intermittent renewable energy resources in the form of chemical bond, such as hydrogen production from electrochemical water splitting, is a promising way to satisfy the future global energy demand and address the environmental issues. Th ...

EPFL2021

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