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We report the influence of N-heterocyclic carbenes (NHCs) on the hydrolysis of a diphosphene TerP?PTer (1; Ter = 2,6-Mes(2)C(6)H(3); Mes = 2,4,6-Me3C6H2), a phosphorus-analogue of an alkene. The diphosphene 1 itself is completely inert towards water. Howev ...
ROYAL SOC CHEMISTRY2020
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Studying carbon dynamics in the coral holobiont provides essential knowledge of nutritional strategies and is thus central to understanding coral ecophysiology. In this study, we assessed the carbon budget in Pocillopora damicornis (usingH13CO3) as a funct ...
2020
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OLED technology beyond small or expensive devices requires light-emitters, luminophores, based on earth-abundant elements. Understanding and experimental verification of charge transfer in luminophores are needed for this development. An organometallic mul ...
Hazardous chemicals excruciatingly contaminated water, air, and soil for the past few decades. Eco-friendly techniques to clean and or destroy these harmful chemicals is an urgent requirement at this moment. In this direction, a large number of methodologi ...
The optoelectronic properties of various carbon allotropes and nanomaterials have been well established, while the purely sp-hybridized carbyne remains synthetically inaccessible. Its properties have therefore frequently been extrapolated from those of def ...
Vast amounts of phosphogypsum (PG) which is a by-product of phosphorous acid production from apatite rock using sulphuric acid, are deposited in large piles at many locations worldwide. PG materials are added at rates of the order of megatonnes (Mt) per an ...
Paul Scherrer Institute, World Resources Forum2019
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Black phosphorus (BP) is a semiconducting material with a direct finite band gap in its monolayer, attracting intense attention for its application in field-effect transistors. However, strong Fermi level pinning (FLP) has been observed for contacts betwee ...
This study describes seasonal water quality parameters measured in Petrozavodsk Bay, Lake Onego, Russia. Petrozavodsk Bay (PB) lies in the north of Lake Onego and adjacent to the city of Petrozavodsk. PB water quality is controlled by anthropogenic input, ...
2019
The analysis of concentration-discharge (C-Q) relationships provides useful information on the processes controlling the mobilization and delivery of chemical elements into streams as well as biogeochemical transformations in river networks. Previous metri ...
2019
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With its tunable band-gap and its unique optical and electronic properties black phosphorus (BP) opens exciting opportunities for optoelectronic nanotechnology. The band-gap extends from the visible to the mid-infrared spectral range, as a function of samp ...
