Related publications (21)

Stabilization strategies in biomass depolymerization using chemical functionalization

Jeremy Luterbacher, Ydna Marie Questell-Santiago

A central feature of most lignocellulosic-biomass-valorization strategies is the depolymerization of all its three major constituents: cellulose and hemicellulose to simple sugars, and lignin to phenolic monomers. However, reactive intermediates, generally ...
NATURE PUBLISHING GROUP2020

Organocatalysts in C-N Bond Forming Reactions of Amines with CO2

Martin Hulla

The thesis describes a simple approach for N-formylation of amines with CO2 and hydrosilane reducing agents, the use of organic salts as N-formylation catalysts, their physical properties required for high catalytic activity and their role in the catalytic ...
EPFL2019

Leather-Promoted Transformation of Glucose into 5-Hydroxymethylfurfural and Levoglucosenone

Paul Joseph Dyson, Felix Daniel Bobbink, Florent Menoud, Zhangjun Huang

The search for efficient catalysts frequently leads to new homogeneous and heterogeneous catalysts of increasing complexity, and sometimes common, natural, or hybrid natural/synthetic materials that could be used in catalysis are overlooked. For example, t ...
2019

Orientation, rotation and solvation of ions in helium nanodroplets

Verónica Oliver Álvarez de Lara

Helium nanodroplets are liquid, finite size, nanoscale helium clusters that have been employed since the 1990s as a matrix for high-resolution spectroscopy of molecules. Spectroscopic studies of ionic species inside helium droplets were not however realise ...
EPFL2019

α-Diimines as Versatile, Derivatizable Ligands in Ruthenium(II) p-Cymene Anticancer Complexes

Paul Joseph Dyson, Lucinda Kate Batchelor

α-Diimines are among the most robust and versatile ligands available in synthetic coordination chemistry, possessing finely tunable steric and electronic properties. A series of novel cationic ruthenium(II) p-cymene complexes bearing simple α-diimine ligan ...
2018

Characterisation and hydration of ye'elimite containing cements

Frank Bullerjahn

Calcium sulphoaluminate cements (CSA) with the main phase ye’elimite are a promising class of non-Portland cements which are gaining increasing interest from the cement industry. However, the hydration kinetics of CSA cements varies strongly, even for ce ...
EPFL2018

Transition metal clusters on h-BN/Rh(111)

Hamed Achour

The main aim of this dissertation is to study the catalytic aspects of very small transition metal clusters supported on h-BN/Rh(111). The catalytic reactions of interest were ammonia synthesis and CO oxidation on mass selected and soft landed iron and pla ...
EPFL2017

A silica-based magnetic platform decorated with mixed ligand gold nanoparticles: a recyclable catalyst for esterification reactions

Francesco Stellacci, Randy Patrick Carney, Elif Ertem Bekdemir, Emma-Rose Janecek

A novel and convenient synthetic strategy for the preparation of magnetically responsive silica nanospheres decorated with mixed ligand protected gold nanoparticles is described. Gold nanoparticles are attached to the silica surface via stable amide bond f ...
Royal Society of Chemistry2016

Furfural production from empty fruit bunch - A biorefinery approach

Edgard Gnansounou, Jegannathan Kenthorai Raman

Biofuels production from agriculture residues is gaining much attention in Brazil due to agriculture residue availability, environmental benign properties of the fuel and, the capacity to improve rural development. However, for consideration of rational us ...
Elsevier2015

Interactions between alite and C(3)A-gypsum hydrations in model cements

Karen Scrivener, Alexandra Quennoz

This paper focuses on the interactions that occur between cement phases during early hydration, especially between the hydration of alite and C(3)A-gypsum. This study shows that alite reaction is accelerated in the presence of gypsum. This acceleration was ...
Pergamon-Elsevier Science Ltd2013

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