Cellophane

Cellophane is a thin, transparent sheet made of regenerated cellulose. Its low permeability to air, oils, greases, bacteria, and liquid water makes it useful for food packaging. Cellophane is highly permeable to water vapour, but may be coated with nitrocellulose lacquer to prevent this. Cellophane is also used in transparent pressure-sensitive tape, tubing and many other similar applications. Cellophane is compostable and biodegradable, and can be obtained from biomaterials. Production, however, uses carbon disulfide (CS2), which has been found to be highly toxic to workers. The lyocell process, however, can be used to produce cellulose film without involving carbon disulfide. "Cellophane" is a generic term in some countries, while in other countries it is a registered trademark. Cellulose from wood, cotton, hemp, or other sources is dissolved in alkali and carbon disulfide to make a solution called viscose, which is then extruded through a slit into a bath of dilute sulfuric acid and sodium sulfate to reconvert the viscose into cellulose. The film is then passed through several more baths, one to remove sulfur, one to bleach the film, and one to add softening materials such as glycerin to prevent the film from becoming brittle. A similar process, using a hole (a spinneret) instead of a slit, is used to make a fibre called rayon. Chemically, cellophane, rayon and cellulose are polymers of glucose; they differ structurally rather than chemically. Cellophane was invented by Swiss chemist Jacques E. Brandenberger while employed by Blanchisserie et Teinturerie de Thaon. In 1900, inspired by seeing wine spill on a restaurant's tablecloth, he decided to create a cloth that could repel liquids rather than absorb them. His first step was to spray a waterproof coating onto fabric, and he opted to try viscose. The resultant coated fabric was far too stiff, but the diaphanous film coating could be separated from the backing cloth easily and in one undamaged piece. Seeing the possibilities of this new material on its own, Brandenberger soon abandoned his original idea.