Publications related to Metallophilic interaction

Gold Chain Formation via Local Lifting of Surface Reconstruction by Hot Electron Injection on H-2(D-2)/Au(111)

Klaus Kern, Anna Maria Roslawska, Abhishek Grewal

The hexagonal close packed surface of gold shows a 22 x root 3 "herringbone" surface reconstruction which makes it unique among the (111) surfaces of all metals. This long-range energetically favored dislocation pattern appears in response to the strong te ...

AMER CHEMICAL SOC2020

Development of Palladium Surface-Enriched Heteronuclear Au-Pd Nanoparticle Dehalogenation Catalysts in an Ionic Liquid

Paul Joseph Dyson, Gabor Laurenczy, Ning Yan, Yuan Yuan, Xi Chen, Xiao Yuan

Heteronuclear Au–Pd nanoparticles were prepared and immobilized in the functionalized ionic liquid [C2OHmim][NTf2]. The structural and electronic properties of the nanoparticles were characterized by a range of techniques and the surface of the nanoparticl ...

Wiley-Blackwell2013

Computational Quantum Chemical Studies on Radicals

Peter Rudolf Tentscher

Radicals play an important role in many areas of chemistry, such as atmospheric, aquatic, polymer, and biological, to name a few. Radicals are often highly reactive species which are short-lived and therefore harder to study by experimental techniques. In ...

EPFL2013

Rationalization of Solvation and Stabilization of Palladium Nanoparticles in Imidazolium-Based Ionic Liquids by DFT and Vibrational Spectroscopy

Paul Joseph Dyson, Ning Yan, Xiao Yuan

A combined DFT/vibrational spectroscopy approach is used to determine the interactions of the 1,3-dimethylimidazolium ([Mmim]+) and 1-ethyl-3-methylimidazolium ([Emim]+) cations and [BF4]- anions with each other in the liquid state and with Pd nanoparticle ...

2012

Thiolato gold(I) complexes containing water-soluble phosphane ligands: a characterization of their chemical and biological properties

Angela Casini, Catherine Marie Amélie Clavel, elena vergara

A series of thiolate gold(I) derivatives bearing water soluble phosphanes - namely sodium triphenylphosphane monosulfonate (TPPMS), sodium triphenylphosphane trisulfonate (TPPTS), 1,3,5-triaza-7-phosphaadamantane (PTA) and 3,7-diacetyl-1,3,7-triaza-5-phosp ...

2011

Hermetic package for optical MEMS

Peter Ryser, Jacques Jacot, Thomas Maeder, Yannick Sébastien Fournier, Frank Seigneur

This article describes the design and fabrication of a hermetic LTCC package for an optical MEMS chip designed for space applications. The package must ensure electrical and optical connections, mechanical positioning, atmosphere control, and finally low t ...

2009

Hermetic package for optical MEMS

Peter Ryser, Jacques Jacot, Thomas Maeder, Yannick Sébastien Fournier, Frank Seigneur

This article describes the design and fabrication of a hermetic LTCC package for an optical MEMS chip designed for space applications. The package must ensure electrical and optical connections, mechanical positioning, atmosphere control, and finally low t ...

2008

Isolation of an intermediate during the decomposition of a tetragold-phosphane complex

Paul Joseph Dyson, Zhaofu Fei

Reaction of the diphosphanylamine 2,6-{(Ph2P)(2)N)(2)C5H3N with four equivalents of Au(tht)Cl (tht = tetrahydrothiophene) affords the tetragold complex 2,6{(ClAuPh2P)(2)N)(2)C5H3N in high yield. Decomposition of the tetragold compound results in the format ...

2004

Metallophilic interaction

Gold Chain Formation via Local Lifting of Surface Reconstruction by Hot Electron Injection on H-2(D-2)/Au(111)

Development of Palladium Surface-Enriched Heteronuclear Au-Pd Nanoparticle Dehalogenation Catalysts in an Ionic Liquid

Computational Quantum Chemical Studies on Radicals

Rationalization of Solvation and Stabilization of Palladium Nanoparticles in Imidazolium-Based Ionic Liquids by DFT and Vibrational Spectroscopy

Thiolato gold(I) complexes containing water-soluble phosphane ligands: a characterization of their chemical and biological properties

Hermetic package for optical MEMS

Hermetic package for optical MEMS

Isolation of an intermediate during the decomposition of a tetragold-phosphane complex

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Hermetic package for optical MEMS

Rationalization of Solvation and Stabilization of Palladium Nanoparticles in Imidazolium-Based Ionic Liquids by DFT and Vibrational Spectroscopy

Gold Chain Formation via Local Lifting of Surface Reconstruction by Hot Electron Injection on H-2(D-2)/Au(111)

Thiolato gold(I) complexes containing water-soluble phosphane ligands: a characterization of their chemical and biological properties

Hermetic package for optical MEMS

Development of Palladium Surface-Enriched Heteronuclear Au-Pd Nanoparticle Dehalogenation Catalysts in an Ionic Liquid

Computational Quantum Chemical Studies on Radicals

Isolation of an intermediate during the decomposition of a tetragold-phosphane complex