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Concept
Kerogen
Summary
Kerogen is solid, insoluble organic matter in sedimentary rocks. It consists of a variety of organic materials, including dead plants, algae, and other microorganisms, that have been compressed and heated by geological processes. Altogether kerogen is estimated to contain 1016 tons of carbon. This makes it the most abundant source of organic compounds on earth, exceeding the total organic content of living matter 10,000-fold.
The type of kerogen present in a particular rock formation depends the type of organic material that was originally present. Kerogen can be classified by these origins: lacustrine (e.g., algal), marine (e.g., planktonic), and terrestrial (e.g., pollen and spores). The type of kerogen depends also on the degree of heat and pressure it has been subjected to, and the length of time the geological processes ran. The result is that a complex mixture of organic compounds reside in sedimentary rocks, serving as the precursor for the formation of hydrocarbons such as oil and gas. In short, kerogen amounts to fossilized organic matter that has been buried and subjected to high temperatures and pressures over millions of years, resulting in various chemical reactions and transformations.
Kerogen is insoluble in normal organic solvents and it does not have a specific chemical formula. Upon heating, kerogen converts in part to liquid and gaseous hydrocarbons. Petroleum and natural gas form from kerogen. The name "kerogen" was introduced by the Scottish organic chemist Alexander Crum Brown in 1906, derived from the Greek for "wax birth" (Greek: κηρός "wax" and -gen, γένεση "birth").
The increased production of hydrocarbons from shale has motivated a revival of research into the composition, structure, and properties of kerogen. Many studies have documented dramatic and systematic changes in kerogen composition across the range of thermal maturity relevant to the oil and gas industry. Analyses of kerogen are generally performed on samples prepared by acid demineralization with critical point drying, which isolates kerogen from the rock matrix without altering its chemical composition or microstructure.
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