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The reaction of [ReBr3(CO)(3)]NEt4 with 3-hydroxy-1,2,3-benzotriazine-4 (3 H) -one in the presence of base gave the ionic rhenium complex [ReBr(C7H4N3O2)(CO)(3)][NEt4] (2) which was crystallographically characterized. A neutral metallamacrocycle 3 was ...
Zirconium nitride has been proposed as inert matrix material to burn plutonium or to transmute long-lived actinides in accelerator-driven sub-critical systems or fast reactors. In combination with the possibility to fabricate specially shaped fuel pellets, ...
Abstract: Inert and optically active pseudo-octahedral CrIIIN6 and RuIIN6 chromophores have been incorporated by self-assembly into heterobimetallic triple-stranded helicates HHH-[CrLnL3]6+ and HHH-[RuLnL3]5+. The crystal structures of CrLnL36 (L ...
High-fluence proton irradiation experiments with thin actinide targets are part of PSI's programme related to accelerator-based transmutation studies. The aim is to provide experimental data for the validation of theoretical models in nucleon-meson transpo ...
A photovoltaic cell comprising: a light transmitting electrically conductive layer deposited on a glass plate or a transparent polymer sheet to which a series of titanium dioxide layers have been applied, in which at least the last titanium dioxide layer ( ...
