Publications related to Radical anion

Bacterial inactivation in sunlit surface waters is dominated by reactive species that emanate from the synergy between light, iron, and natural organic matter

César Pulgarin, Stefanos Giannakis, Jun Ma, Da Wang, Shuang Song

In this study, the synergistic and antagonistic effects of Fe species and coexisting natural organic matter (NOM) on the efficacy of solar light disinfection of water are investigated. Different initial iron species (Fe2+/Fe3+) and naturalorganic matter ty ...

Amsterdam2023

Oxidase-Type C-H/C-H Coupling Using an Isoquinoline-Derived Organic Photocatalyst

Xile Hu, Lei Zhang

Oxidase-type oxidation is an attractive strategy in organic synthesis due to the use of O-2 as the terminal oxidant. Organic photocatalysis can effect metal-free oxidase chemistry. Nevertheless, current methods are limited in reaction scope, possibly due t ...

WILEY-V C H VERLAG GMBH2022

Co(III) carboxamide complexes as electrocatalysts for water splitting

Kurt Schenk, Farzaneh Fadaei Tirani

Water splitting is a promising approach for storing intermittent renewable energies, such as sunlight in the clean chemical bonds as a hydrogen fuel. Two water-soluble octahedral cobalt (III) complexes, [Co(bpb)(OAc)(H2O)], 1, (bpb(2-) = N,N' -bis[(2-pyrid ...

PERGAMON-ELSEVIER SCIENCE LTD2022

Optical properties and photochemical production of hydroxyl radical and singlet oxygen after ozonation of dissolved organic matter

Urs von Gunten, Frank Jonathan Leresche

This study focuses on the effects of ozonation on the optical and photochemical properties of dissolved organic matter (DOM). Upon ozonation, a decrease in light absorption properties of DOM was observed concomitantly with a large increase in singlet oxyge ...

ROYAL SOC CHEMISTRY2021

New Strategies for the Functionalization of Alkenes Exploiting Tethering Chemistry and Ring Strain

Bastian Antoine Rodolphe Claude Muriel

Amino alcohols, cyclopropanes and nitriles are privileged structural motifs found in the scaffold of natural products and bioactive compounds. In addition, they are versatile building blocks in organic chemistry. The development of new and increasingly eff ...

EPFL2021

Evidence of Large Polarons in Photoemission Band Mapping of the Perovskite Semiconductor CsPbBr3

Matthias Wolf, Majed Chergui, Nicola Marzari, Marco Grioni, Nicola Colonna, Alberto Crepaldi, Gianmarco Gatti, Serhii Polishchuk, Thomas Roland Barillot

Lead-halide perovskite (LHP) semiconductors are emergent optoelectronic materials with outstanding transport properties which are not yet fully understood. We find signatures of large polaron formation in the electronic structure of the inorganic LHP CsPbB ...

AMER PHYSICAL SOC2020

Laser flash photolysis study of the photoinduced oxidation of 4-(dimethylamino)benzonitrile (DMABN)

Urs von Gunten, Frank Jonathan Leresche, Silvio Canonica

Aromatic amines are aquatic contaminants for which phototransformation in surface waters can be induced by excited triplet states of dissolved organic matter ((DOM)-D-3*). The first reaction step is assumed to consist of a one-electron oxidation process of ...

ROYAL SOC CHEMISTRY2019

Photoelectrocatalytic arene C–H amination

Xile Hu, Lei Zhang, Jingshan Luo, Dan Ren, Laurent Liardet

Photoelectrochemical cells are widely studied for solar energy conversion. However, they have rarely been used for the synthesis of high added-value organic molecules. Here we describe a strategy to use haematite, an abundant and robust photoanode, for non ...

2019

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Radical anion

Bacterial inactivation in sunlit surface waters is dominated by reactive species that emanate from the synergy between light, iron, and natural organic matter

Self-Interaction and Polarons in Density Functional Theory

Oxidase-Type C-H/C-H Coupling Using an Isoquinoline-Derived Organic Photocatalyst

Co(III) carboxamide complexes as electrocatalysts for water splitting

Optical properties and photochemical production of hydroxyl radical and singlet oxygen after ozonation of dissolved organic matter

New Strategies for the Functionalization of Alkenes Exploiting Tethering Chemistry and Ring Strain

Copper-catalyzed transformations of carboradicals generated by electrochemical and photochemical methods: oxidative amination and polyfluoroarylation

Evidence of Large Polarons in Photoemission Band Mapping of the Perovskite Semiconductor CsPbBr3

Laser flash photolysis study of the photoinduced oxidation of 4-(dimethylamino)benzonitrile (DMABN)

Photoelectrocatalytic arene C–H amination

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New Strategies for the Functionalization of Alkenes Exploiting Tethering Chemistry and Ring Strain

Evidence of Large Polarons in Photoemission Band Mapping of the Perovskite Semiconductor CsPbBr3

Self-Interaction and Polarons in Density Functional Theory

Co(III) carboxamide complexes as electrocatalysts for water splitting

Optical properties and photochemical production of hydroxyl radical and singlet oxygen after ozonation of dissolved organic matter

Laser flash photolysis study of the photoinduced oxidation of 4-(dimethylamino)benzonitrile (DMABN)

Copper-catalyzed transformations of carboradicals generated by electrochemical and photochemical methods: oxidative amination and polyfluoroarylation

Bacterial inactivation in sunlit surface waters is dominated by reactive species that emanate from the synergy between light, iron, and natural organic matter

Photoelectrocatalytic arene C–H amination

Oxidase-Type C-H/C-H Coupling Using an Isoquinoline-Derived Organic Photocatalyst