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Concept
Crazing
Summary
Crazing is the phenomenon that produces a network of fine cracks on the surface of a material, for example in a glaze layer. Crazing frequently precedes fracture in some glassy thermoplastic polymers. As it only takes place under tensile stress, the plane of the crazing corresponds to the stress direction. The effect is visibly distinguishable from other types of fine cracking because the crazing region has different refractive indices from surrounding material. Crazing occurs in regions of high hydrostatic tension, or in regions of very localized yielding, which leads to the formation of interpenetrating microvoids and small fibrils. If an applied tensile load is sufficient, these bridges elongate and break, causing the microvoids to grow and coalesce; as microvoids coalesce, cracks begin to form.
Crazing occurs in polymers, because the material is held together by a combination of weaker Van der Waals forces and stronger covalent bonds. Sufficient local stress overcomes the Van der Waals force, allowing a narrow gap. Once the slack is taken out of the backbone chain, covalent bonds holding the chain together hinder further widening of the gap. The gaps in a craze are microscopic in size. Crazes can be seen because light reflects off the surfaces of the gaps. The gaps are bridged by fine filament called fibrils, which are molecules of the stretched backbone chain. The fibrils are only a few nanometers in diameter, and cannot be seen with a light microscope, but are visible with an electron microscope.
The thickness profile of a crazing is like a sewing needle: the very tip of the crazing may be as thin as several atoms. As the distance from the tip increase, it tends to thicken gradually with the rate of the increase diminishing with distance. Therefore, the growth of crazing has a critical distance from the tip. The opening angle of the crazing lies between 2° and 10°. The boundary between crazing and surrounding bulk polymer is very sharp, the microstructure of which can be scaled down to 20Å or less, which means it can only be observed by electron microscopy.
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