Concept
Metallocene
Related publications (49)
Disorder and Halide Distributions in Cesium Lead Halide Nanocrystals as Seen by Colloidal 133Cs Nuclear Magnetic Resonance Spectroscopy
Colloidal nuclear magnetic resonance (cNMR) spectroscopy on inorganic cesium lead halide nanocrystals (CsPbX3 NCs) is found to serve for noninvasive characterization and quantification of disorder within these structurally soft and labile particles. In par ...
Washington2024Reactivity and biological activity of N,N,S-Schiff-base rhodium pentamethylcyclopentadienyl complexes
Paul Joseph Dyson, Lucinda Kate Batchelor
Neutral piano-stool complexes of the general formula [(eta(5)-C5Me5)Rh(L-OR)] (R = Me, 1; R = Et, 2; R = Pe(i), 3) have been prepared in alcohols (methanol, 1; ethanol, 2; isopropanol, 3) from the Schiff-base 5-methyl-4-{(pyridin-2-ylmethylene)amino}-4H-1, ...
ELSEVIER SCIENCE SA2020Stability and Degradation Mechanisms of Copper-Based Catalysts for Electrochemical CO2 Reduction
Raffaella Buonsanti, Jan Vávra
To date, copper is the only monometallic catalyst that can electrochemically reduce CO2 into high value and energy-dense products, such as hydrocarbons and alcohols. In recent years, great efforts have been directed towards understanding how its nanoscale ...
2020Digestive-Ripening-Facilitated Nanoengineering of Diverse Bimetallic Nanostructures
From an ingenious methodology for obtaining monodispersity, digestive ripening has advanced to become an outstanding solution-based synthesis route to realizing various bimetallic heterostructures. This feature article attempts to provide an overview of th ...
AMER CHEMICAL SOC2019Anticancer Potential of Diiron Vinyliminium Complexes
Paul Joseph Dyson, Lucinda Kate Batchelor, Silvia Schoch
Although ferrocene derivatives have attracted considerable attention as possible anticancer agents, the medicinal potential of diiron complexes has remained largely unexplored. Herein, we describe the straightforward multigram-scale synthesis and the antip ...
WILEY-V C H VERLAG GMBH2019Mechanistic study of the photo‐generation of hydrogen by decamethylruthenocene
Hubert Girault, Pekka Eero Peljo, Manuel Alejandro Méndez Agudelo, Heron Vrubel, Micheal Diarmaid Scanlon, Laurent Alexis Clément Vannay, Sunny Isaïe Maye, Lucie Josette Renée Rivier
Hydrogen evolution by decamethylruthenocene (Cp*2RuII) was studied in detail highlighting that metallocenes are capable of photo‐reducing hydrogen without the need of an additional sensitizer. Electrochemical, gas chromatographic and spectroscopic (UV/vis, ...
2019Synthesis and In Vitro (Anticancer) Evaluation of eta(6)-Arene Ruthenium Complexes Bearing Stannyl Ligands
Paul Joseph Dyson, Tina Riedel
Treatment of the known half-sandwich complexes of the type [(eta(6)-C6H6)RuCl2(P(OR)(3))] (R = Me or Ph) with SnCl2 yielded three new half-sandwich ruthenium complexes (C1-C3): [(eta(6)-C6H6)RuCl(SnCl3)(P(OMe)(3))] (C1), [(eta(6)-C6H6)RuCl(SnCl3)(P(OPh)(3) ...
2017A Monometallic Iron(I) Organoferrate
Xile Hu, Matthew Wodrich, Fedor Zhurkin
Tetra-n-butylammonium (TBA) (eta(6)-biphenyl)diphenyfferrate was formed unexpectedly in the reaction of (TBA)(2)[Fe4S4Cl4] with an excess of phenyllithium. This complex belongs to a novel type of organoferrate. ...
American Chemical Society2017Leaching from Palladium Nanoparticles in an Ionic Liquid Leads to the Formation of Ionic Monometallic Species
Molecular dynamics simulations and DFT calculations suggest that leaching of palladium species from Pd nanoparticles in ionic liquids does not involve "naked" Pd(0) atoms or neutral ArPdX species formed by oxidative addition of arylhalides. Instead, the io ...
Amer Chemical Soc2017Reduction of a Cerium(III) Siloxide Complex To Afford a Quadruple-Decker Arene-Bridged Cerium(II) Sandwich
Rosario Scopelliti, Marinella Mazzanti, Rory Patrick Kelly
Organometallic multi-decker sandwich complexes containing f-elements remain rare, despite their attractive magnetic and electronic properties. The reduction of the Ce-III siloxide complex, [KCeL4] (1; L = OSi(OtBu)(3)), with excess potassium in a THF/tolue ...
2017