Corrosion inhibitor | EPFL Graph Search

In chemistry, a corrosion inhibitor or anti-corrosive is a chemical compound that, when added to a liquid or gas, decreases the corrosion rate of a material, typically a metal or an alloy, that comes into contact with the fluid. The effectiveness of a corrosion inhibitor depends on fluid composition, quantity of water, and flow regime. Corrosion inhibitors are common in industry, and also found in over-the-counter products, typically in spray form in combination with a lubricant and sometimes a penetrating oil. They may be added to water to prevent leaching of lead or copper from pipes. A common mechanism for inhibiting corrosion involves formation of a coating, often a passivation layer, which prevents access of the corrosive substance to the metal. Permanent treatments such as chrome plating are not generally considered inhibitors, however: corrosion inhibitors are additives to the fluids that surround the metal or related object. Types The nature of the corrosive inhib

Stability and physical properties of alkylsilane and alkylphosphonate self-assembled monolayer (SAM) films on metal oxide substrates characterized at the micro- and nanoscale

Enamul Hoque

Self-assembled monolayer (SAM) films have attracted immense attention for both fundamental and applied research. A SAM is composed of a large number of molecules with a head group that chemisorbs onto a substrate, a tail group that interacts with the outer surface of the film, and a spacer (backbone) chain group that connects the head and tail groups resulting in a coating. Interactions between spacer groups of different molecules, such as van der Waals forces and/or hydrogen bonding, hasten SAM film formation and contribute to its stability. In this dissertation, SAM and thin films have been formed onto copper and aluminum oxide surfaces by reaction with 1H,1H,2H,2H-perfluorodecyldimethylchlorosilane (PFMS), 1H,1H,2H,2H-perfluorodecyltrichlorosilane (PFTS), 1H,1H,2H,2H-perfluorodecylphosphonic acid (PFDP), octylphosphonic acid (OP), decylphosphonic acid (DP), and octadecylphosphonic acid (ODP). The properties and stability of the films were investigated employing complementary surface analysis techniques: X-ray photoelectron spectroscopy (XPS), atomic force microscopy (AFM), friction force microscopy (FFM), a derivative of AFM, contact angle measurements (CAMs), and Fourier transform infrared reflection/absorption spectroscopy (FT-IRRAS). The perfluoroalkylsilane SAM on Cu is found to be extremely hydrophobic typically having sessile drop static contact angles of more than 130° for pure water and a surface energy of 14 mJ/m2 (mN/m). FFM showed a significant reduction in the adhesive force and friction coefficient of PFMS modified Cu (PFMS/Cu) compared to unmodified Cu. Treatment by exposure to harsh conditions showed that PFMS/Cu SAM can withstand boiling nitric acid (pH=1.8), boiling water, and warm sodium hydroxide (pH=12, 60 °C) solutions for at least 30 minutes. Furthermore, no SAM degradation was observed when PFMS/Cu was exposed to warm nitric acid solution for up to 70 min at 60 °C or 50 min at 80 °C. XPS and FT-IRRAS data reveal a coordination of the PFMS silicon (Si) atom with a cuprate (CuO) molecule present on the oxidized copper substrate. The data give good evidence that the stability of the SAM film on the PFMS modified oxidized Cu surface is largely due to the formation of a siloxy-copper (-Si-O-Cu-) bond via a condensation reaction between silanol (-Si-OH) and copper hydroxide (CuOH). For a PFTS modified Cu surface (PFTS/Cu), the sessile drop static contact angle of pure water has been measured to be more than 125° and the surface energy to be typically less than 16 mJ/m2. Stability tests show that the PFTS/Cu film can survive in boiling pure water for one hour, boiling nitric acid (pH 1.5 or 1.8) for 30 minutes, sodium hydroxide solution (pH 12, 70 °C) for 30 minutes, and autoclave conditions (steam at 134 °C and 3 atmospheres) for 15 minutes. The more commonly used self-assembled monolayer (SAM) modifications of Cu surfaces, e.g. thiol compounds, are significantly less stable than PFTS/Cu. Extremely hydrophobic (low surface energy) and stable PFMS/Cu SAMs and PFTS/Cu films could be useful as corrosion inhibitors in micro/nanoelectronic devices and/or as promoters for anti-wetting, low adhesion surfaces or drop-wise condensation on heat exchange surfaces. XPS analysis confirmed the presence of perfluorinated and non-perfluorinated alkylphosphonate molecules on the PFDP, DP, and ODP SAMs deposited at the aluminum oxide coated silicon (Al/Si) surfaces. The sessile drop static contact angle of pure water on PFDP SAMs was typically more than 130° and on DP and ODP typically more than 125° indicating that the phosphonic acid SAMs reacted with Al samples were very hydrophobic. The surface roughness for PFDP/Al, DP/Al, ODP/Al, and bare Al was approximately 35 nm, as determined by AFM. The surface energy for PFDP/Al was determined to be approximately 11 mJ/m2 by the Zisman plot method compared to 21 mJ/m2 and 20 mJ/m2 for DP/Al and ODP/Al, respectively. PFDP/Al gave the lowest adhesion and friction force while bare Al gave the highest. The adhesion and friction forces for ODP/Al and DP/Al SAMs were in between. ODP, DP, and OP SAMs have been studied in detail on relatively flat aluminum oxide surfaces. The rms surface roughness for ODP/Al, DP/Al, OP/Al, and bare Al was less than 15 nm, as determined by AFM. The sessile drop static contact angle of pure water on ODP/Al and DP/Al was typically more than 115° and on OP/Al typically less than 105°. The surface energy for ODP/Al and DP/Al was determined to be approximately 21 mJ/m2 and 22 mJ/m2, respectively, compared to 26 mJ/m2 for OP/Al. ODP/Al and OP/Al were studied by FFM to better understand their micro-/nano-tribological properties. ODP/Al gave the lowest coefficient of friction values while bare Al gave the highest. The adhesion forces for ODP/Al and OP/Al were comparable. The chemical stability of ODP/Al, PFDP/Al, DP/Al, OP/Al, and PFMS/Al SAMs has been inspected by exposure to warm nitric acid (pH 1.8, 30 min, 60-95 °C). The XPS data and stability against harsh chemical conditions indicate that a type of bond forms between a phosphonic acid (PA) or silane molecule and the oxidized Al surface. Stability tests using warm nitric acid (pH 1.8, 30 min, 60-95 °C) show ODP/Al SAMs to be most stable followed by PFDP/Al, DP/Al, PFMS/Al, and OP/Al SAMs. For PFTS/Al, stability tests demonstrate that modified aluminum is able to survive exposure to warm nitric acid (pH = 1.8, 60 °C, 30 min) indicating some degree of robustness. Hydrophobic, low adhesion, and robust aluminum surfaces have useful applications for micro/nano-electromechanical systems (MEMS/NEMS), such as digital micro-mirror devices (DMDs). These studies are expected to aid in the design and selection of proper lubricants for MEMS/NEMS.

EPFL2007

Modèle d'évolution de l'état des ponts-routes en béton

Guido Roelfstra

The management of existing road infrastructures is a multidisciplinary activity that involves structural engineering, material science, management, economics and ecology. The objective is to achieve maximum availability of road links at minimum societal costs. Recently, tools (Bridge Management Systems, BMSs) have been developed to help decision makers to determine the optimal management strategies within available resources. The condition development model is a key element of the BMSs. Currently this model is using empirical approach making use of data collected during inspections and is formulated with Markov chains. The assessment units are structural elements and these are classified into condition classes according to their visual appearance. The condition assessment is therefore rather subjective since no measurements are involved in it. Consequently, the condition development based on visual inspections will reflect this subjectivity. In order to improve the objectivity of condition forecasts physical and chemical phenomena governing deterioration has to be incorporated in the condition development model. Observations made on a bridge sample representative of the Swiss highway bridges showed that chloride-induced corrosion is the main deterioration mechanism. For this reason this research was focused upon modeling the chloride-induced corrosion. In this research, the condition development model is established, based physical and chemical phenomena involved in chloride induced corrosion. This analytical model is able to yield quantitative results on condition development. Accuracy and availability of input data govern the level of accuracy of such an analytical model. The existing knowledge on chloride induced corrosion and inspection techniques available on site are examined in order to develop a simple and reliable condition development model. Firstly, non-destructive testing methods are used in addition to visual observations, to determine quantitative values (permeability and thickness of the concrete cover) of parameters governing the segment deterioration. The structural elements are divided into areas i.e. segments where the parameters governing chloride-induced corrosion are assumed to be constant. It is proposed to divide structural elements into segments based on three concrete cover permeability classes, concrete cover thickness and three types of surface exposures to chloride contaminated water. Secondly, a chloride transport model is developed to simulate the real exposure of reinforcement to chloride contaminated water, taking into consideration the transport mechanisms of water and chloride ions. Simulations are performed for the various segment parameters that have been identified in the segmental approach. Thirdly, a relation is established between the free chloride ion content and the corrosion initiation probability. Using the results of the chloride transport model, the development of the corrosion initiation is determined for road bridges segments. An analysis is made to predict the corrosion initiation time of existing bridges as a function of their segment parameters (exposure and concrete cover permeability and thickness), but also to establish recommendations for the construction of new bridges. Fourthly, the corrosion rate i.e. loss of steel cross-section is then determined according to the concrete cover permeability and the exposure to chloride contaminated water. Fifthly, the results of the presented mode1 are mapped to conditions States as defined in the BMSs. Three degradation matrices (Markov chains) are determined, corresponding to three condition developments: favorable, normal and unfavorable. The three condition developments can be estimated for given quantitative values of the concrete cover permeability, thickness and surface exposure to chloride-contaminated water. In this way, the segment parameters may be used in BMSs to forecasts future condition of segments, elements and the whole structure. Finally the structural behaviour of the concrete road-bridges until failure is studied. The determinant failure scenarios are identified for each bridge type and a case study is performed on the sample representative for the Swiss highway bridges. For this purpose the determinant segments for the structural safety are identified. Additionally the required concrete cover depth for a service life of 50 and 100 years is expressed as a function of the permeability and the exposure to chloride contaminated water. This research outlines the need to measure the concrete cover permeability and thickness with non-destructive test methods as well as to determine the exposure to chloride contaminated water. These values are essential to predict the condition development of concrete road bridges.

EPFL2001