Related publications (66)

Decarbonizing the fertilizers sector: an alternative pathway for urea and nitric acid production

François Maréchal, Daniel Alexander Florez Orrego, Meire Ellen Gorete Ribeiro Domingos

In order to alleviate the environmental impact that nitrogen fertilizers production is responsible for, several efforts have been addressed to incentivize the partial or total decarbonization of the supply chains of ammonia and its derivatives. The decarbo ...
2024

Direct conversion of lignin to functionalized diaryl ethers via oxidative cross-coupling

Paul Joseph Dyson, Mingyang Liu

Efficient valorization of lignin, a sustainable source of functionalized aromatic products, would reduce dependence on fossil-derived feedstocks. Oxidative depolymerization is frequently applied to lignin to generate phenolic mono- mers. However, due to th ...
2023

Selecting Suitable Near-Native Lignins for Research

Jeremy Luterbacher

There are several methods to isolate near-native lignins, including milled-wood lignin, enzymatic lignin, cellulolytic enzyme lignin, and enzymatic mild-acidolysis lignin. Which one is the most representative of the native lignin? Herein, near-native ligni ...
Washington2023

Techno-economic and environmental analysis of high temperature heat pumps integration into industrial processes: the ammonia plant and pulp mill cases

François Maréchal, Daniel Alexander Florez Orrego, Meire Ellen Gorete Ribeiro Domingos

Heat pumps will play an important role in improving the performance of the industrial processes aiming to decarbonize their heating requirements. Yet, defining the best operating conditions of those devices may be a challenging task, as they are embedded i ...
2023

Lignin Hydrogenolysis: Phenolic Monomers from Lignin and Associated Phenolates across Plant Clades

Yuan Li

The chemical complexity of lignin remains a major challengeforlignin valorization into commodity and fine chemicals. A knowledgeof the lignin features that favor its valorization and which plantsproduce such lignins can be used in plant selection or to eng ...
AMER CHEMICAL SOC2023

Isolation of Mixed Compositions of Cellulose Nanocrystals, Microcrystalline Cellulose, and Lignin Nanoparticles from Wood Pulps

Tiffany Abitbol

From a circular economyperspective, one-pot strategies for theisolation of cellulose nanomaterials at a high yield and with multifunctionalproperties are attractive. Here, the effects of lignin content (bleachedvs unbleached softwood kraft pulp) and sulfur ...
AMER CHEMICAL SOC2023

Techno-economic and environmental analysis of methanol and dimethyl ether production from syngas in a kraft pulp process

François Maréchal

The conventional configuration of a pulp mill, in which black liquor is concentrated and burnt, is compared to the upgrading gasification routes for methanol (MeOH) or dimethyl ether (DME) co-production. To this end, various exergy-based and environmental ...
PERGAMON-ELSEVIER SCIENCE LTD2022

Integrated production of chemicals and fuels in the pulp industry: techno-economic and environmental analysis of black liquor gasification-based processes

François Maréchal, Daniel Alexander Florez Orrego, Meire Ellen Gorete Ribeiro Domingos

The pulp and paper sector is classified as an energy intensive activity and several efforts are being made to mitigate its atmospheric emissions, improve the recovery of residual heat and capitalize on its byproducts. The black liquor (BL) is a byproduct o ...
2022

Extraction and controlled functionalization of lignin for materials applications

Stefania Bertella

Lignin is a renewable aromatic polymer that due to its abundance and unique chemical structure is a promising candidate to replace aromatic materials that are currently sourced from fossil oil. The same structure of lignin poses however drawbacks for its v ...
EPFL2022

A study on synergies of combined pulp and fuel production

François Maréchal, Tuong-Van Nguyen, Julia Granacher, Erina Clare Mcdonald

To limit climate change by reducing global greenhouse gas emissions, a transition away from fossil fuels is required. Biofuels represent a promising low carbon alternative for sectors that are hard to electrify, such as aviation. The integration of bio ref ...
2021

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