Concept

Salt metathesis reaction

Related publications (68)

25th Anniversary Article: Label-Free Electrical Biodetection Using Carbon Nanostructures

Nanostructures are promising candidates for use as active materials for the detection of chemical and biological species, mainly due to the high surface-to-volume ratio and the unique physical properties arising at the nanoscale. Among the various nanostru ...

Wiley-V C H Verlag Gmbh2014

Thermal properties of Y(BH 4) 3 synthesized via two different methods

Andreas Züttel

Y(BH4)3 is one of the candidates for solid-state hydrogen storage, which contains 9.06 wt% of hydrogen. In this study, the thermal properties of Y(BH4)3 synthesized via two different methods are extensively examined. One method relies on the solid-solid me ...

2013

Diamine Bis(phenolate) as Supporting Ligands in Organoactinide(IV) Chemistry. Synthesis, Structural Characterization, and Reactivity of Stable Dialkyl Derivatives

Marinella Mazzanti

The homoleptic compounds [U(salan-R2)2] (R = Me (1), tBu (2)) were prepared in high yield by salt-metathesis reactions between UI4(L)2 (L = Et2O, PhCN) and 2 equiv of [K2(salan-R2)] in THF. In contrast, the reaction of the tetradentate ligands salan-R2 wit ...

2013

Insight into the decomposition pathway of the complex hydride Al3Li4(BH4)(13)

Elsa Callini

The decomposition pathway of the complex hydride Al3Li 4(BH4)13 is in the focus of this study. Initially the compound attracted great interest due to its high H2 capacity (17.2 wt.%) and desorption at moderate temperatures (<100 °C). This work sheds lig ...

2013

System for Assessing Classroom Attention

Pierre Dillenbourg, Mirko Raca

In this paper we give a preview of our system for automatically evaluating attention in the classroom. We demonstrate our current behaviour metrics and preliminary observations on how they reflect the reactions of people to the given lecture. We also intro ...

2013

Borophosphonate Cages: Easily Accessible and Constitutionally Dynamic Heterocubane Scaffolds

Rosario Scopelliti, Kay Severin, Laure Menin, Konstantin Zhurov, Justus Tönnemann

A versatile and experimentally facile procedure for the synthesis of borophosphonate cages of the general formula [tBuPO3BR′]4 is described. The method involves heating of tert-butylphosphonic acid with a boronic acid in toluene to give borophosphonates in ...

Wiley-V C H Verlag Gmbh2012

A Pyridinol Acyl Cofactor in the Active Site of [Fe]-hydrogenase Evidenced by the Reactivity of Model Complexes

Xile Hu, Dafa Chen, Bowen Hu

The decomposition reaction of a water-soluble complex (see scheme; 1) in H2O confirms the existence of a unique bidentate pyridinol cofactor in [Fe]-hydrogenase. This unique moiety is confirmed for the first time by the decomposition of a well-defined mode ...

Wiley-V C H Verlag Gmbh2012

Kinetic modelling of batch slurry reactions

Julien Léo Billeter

Slurries are widely used in important chemical and pharmaceutical manufacturing processes. In this presentation we report chemical monitoring and modeling of batch slurry reactions using optical and calorimetric measurement where key analytes are present i ...

2012

Interfacial Self-Assembly of Water-Soluble Cationic Porphyrins for the Reduction of Oxygen to Water

Hubert Girault, Astrid Johana Olaya Avendano, Pierre-François Marie Brevet

Meet at the border: Assembly of the water-soluble cobalt tetrakis(N-methylpyridinium-4-yl)porphyrin [CoTMPyP]4+ at soft interfaces is enhanced and stabilized by its interfacial interaction with the lipophilic anion (C6F5)4B−. The supramolecular structure t ...

2012

Biomimetic Oxygen Reduction by Cofacial Porphyrins at a Liquid-Liquid Interface

Hubert Girault, Pekka Eero Peljo

Oxygen reduction catalyzed by cofacial metalloporphyrins at the 1,2-dichlorobenzene-water interface was studied with two lipophilic electron donors of similar driving force, 1,1'-dimethylferrocene (DMFc) and tetrathiafulvalene (TTF). The reaction produces ...

2012

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