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A review of the recent achievements in an understanding of the synthesis, soln. behavior, structure and bonding of the homopolyat. sulfur cations. A focus is put on the developments aimed to understand exptl. observations, i.e., quantum chem. calcns. of th ...
We record double resonance spectra of the 4nu(1) band of jet-cooled C-13-methanol using single rotational state selection in the nu(1) fundamental and subsequent promotion of the selected molecules to the fourth vibrational level. We then detect transition ...
[Rh-4 (CO)(6) (mu-Me2PCH2PMe2)(3)], the first example of a hexasubstituted derivative of Rh-4(CO)(12), has a ground state geometry in the solid state and in solution of C-s symmetry with four edge-bridging carbonyls and with each diphosphine ligand bridgin ...
The photophysical properties of the triple-stranded dimetallic helicates [Ln2(LC−2H)3]·H2O (Ln = Nd, Sm, Dy, Yb) are determined in water and D2O solutions, and energy transfer processes are modeled for SmIII. The luminescence of NdIII, SmIII, and YbIII is ...
The experimentally observed rise in the single pass methanol production with CO2 and H-2 (T = 200 degreesC, P = 4.3 bar) by in situ product removal over a perm-selective Nafion (R) membrane is verified by model simulations. For this purpose, software was d ...
The spatial and time-reversal symmetries of excitons in quantum wires are discussed, including possible use in numerical computation. Particular attention is paid to the important case of a single symmetry plane (group C-s). Even in such a low symmetry cas ...
We investigate in the simplest compact D = 4 N = 1 type-II B orientifold models the sigma-model symmetry suggested by the proposed duality of these models to heterotic orbifold vacua. This symmetry is known to be present at the classical level, and is asso ...
Due to the ubiquitous presence of a Berry phase, in most cases of dynamical Jahn-Teller systems the symmetry of the vibronic ground state is the same as that of the original degenerate electronic state; As a single exception, the linear H x h icosahedral m ...
The low temperature (LT) modification of Cs3Bi2I9 has been refined to R(F) = 0.055 on the basis of X-ray diffraction measurements at T = 130 K from a twin crystal with six fractions connected by 3-fold axis and m-planes symmetry operations. Data were colle ...
The photophysical properties of the triple-stranded dimetallic helicates [Ln2(LC−2H)3]·H2O (Ln = Nd, Sm, Dy, Yb) are determined in water and D2O solutions, and energy transfer processes are modeled for SmIII. The luminescence of NdIII, SmIII, and YbIII is ...
