A fire retardant is a substance that is used to slow down or stop the spread of fire or reduce its intensity. This is commonly accomplished by chemical reactions that reduce the flammability of fuels or delay their combustion. Fire retardants may also cool the fuel through physical action or endothermic chemical reactions. Fire retardants are available as powder, to be mixed with water, as fire-fighting foams and fire-retardant gels. Fire retardants are also available as coatings or sprays to be applied to an object. Fire retardants are commonly used in fire fighting, where they may be applied aerially or from the ground. In general, fire retardants reduce the flammability of materials by either blocking the fire physically or by initiating a chemical reaction that stops the fire. There are several ways in which the combustion process can be retarded by physical action: By cooling: Some chemical reactions actually cool the material down. By forming a protective layer that prevents the underlying material from igniting. By dilution: Some retardants release water and/or carbon dioxide while burning. This may dilute the radicals in the flame enough for it to go out. Commonly used fire retardant additives include mixtures of huntite and hydromagnesite, aluminium hydroxide, and magnesium hydroxide. When heated, aluminium hydroxide dehydrates to form aluminum oxide (alumina, Al2O3), releasing water vapor in the process. This reaction absorbs a great deal of heat, cooling the material into which it is incorporated. Additionally, the residue of alumina forms a protective layer on the material's surface. Mixtures of huntite and hydromagnesite work in a similar manner. They endothermically decompose releasing both water and carbon dioxide, giving fire retardant properties to the materials in which they are incorporated. Reactions in the gas phase: chemical reactions in the flame (i.e. gas phase) can be interrupted by fire retardants. Generally, these retardants are organic halides (haloalkanes) such as Halon and PhostrEx.
Jeremy Samuel Arey, Saer Samanipour, Petros Dimitriou Christidis, Deedar Nabi