Concept

Phase rule

Related publications (389)

Cu-Sn-S system: Vibrational properties and coexistence of the Cu2SnS3, Cu3SnS4 and Cu4SnS4 compounds

In the present study the transformation between Cu2SnS3, Cu3SnS4 and Cu4SnS4 compounds is analyzed by means of X-ray diffraction and Raman scattering spectroscopy. A detailed analysis of the X-ray diffractograms showed the dependence of formation of the in ...

PERGAMON-ELSEVIER SCIENCE LTD2020

Biaxial flexural fatigue behavior of strain-hardening UHPFRC thin slab elements

Eugen Brühwiler, Xiujiang Shen

The biaxial flexural fatigue behavior of thin slab elements made of strain-hardening Ultra High Performance Fiber Reinforced Cementitious Composite (UHPFRC) is investigated experimentally by means of the ring-on-ring test method. Fourteen flexural fatigue ...

2020

Characterization of local morphology and availability of triple-phase boundaries in solid oxide cell electrodes

Jan Van Herle, Marco Cantoni, Arata Nakajo, Pierre Burdet, Giorgio Rinaldi

The performance of solid oxide cells is known to be dependent upon the density of three phase boundaries (TPB), but the potential for improving their effective electrocatalytic activity by morphological adjustments is imprecisely known. A spilling algorith ...

2019

Quantum phase transitions beyond Landau-Ginzburg theory in one-dimensional space revisited

The phase diagram of the quantum spin-1/2 antiferromagnetic J(1)-J(2) XXZ chain was obtained by Haldane using bosonization techniques [Haldane, Phys. Rev. B 25, 4925 (1982); 26, 5257 (1982)]. It supports three distinct phases for 0

2019

Anisotropic exchange Hamiltonian, magnetic phase diagram, and domain inversion of Nd2Zr2O7

We present thermodynamic and neutron-scattering measurements on the quantum spin ice candidate Nd2Zr2O7. The parametrization of the anisotropic exchange Hamiltonian is refined based on high-energyresolution inelastic neutron-scattering data together with t ...

AMER PHYSICAL SOC2019

Water Activity from Equilibrium Molecular Dynamics Simulations and Kirkwood-Buff Theory

Satoshi Takahama, Mária Lbadaoui-Darvas

Water activity and related thermodynamic properties are calculated for several aqueous solutions using equilibrium molecular dynamics in conjunction with the recent extension of the Kirkwood-Buff (KB) theory for closed systems. The general applicability of ...

AMER CHEMICAL SOC2019

Determining the phase diagram of atomically thin layered antiferromagnet CrCl3

Dumitru Dumcenco, Marco Gibertini, Zhe Wang

Changes in the spin configuration of atomically thin, magnetic van der Waals multilayers can cause drastic modifications in their opto-electronic properties. Conversely, the opto-electronic response of these systems provides information about the magnetic ...

NATURE PUBLISHING GROUP2019

Thermodynamic re-assessment of the Zn–P binary system

Anna Fontcuberta i Morral, Elias Zsolt Stutz, Mahdi Zamani, Simon Robert Escobar Steinvall

Thermodynamic phase diagrams are the cornerstones to develop synthesis of new materials. Zinc phosphide has evolved into a prospective semicontuctor for next generation solar cells, thanks to its abundance and functional properties. Here we derive an optim ...

2019

Synthesis, Characterization, and Applications of Visible Light Active Metal-Organic Frameworks

Samantha Lynn Anderson

Understanding how crystalline materials are assembled is important for the rational design of metal-organic frameworks (MOFs). Controlling their formation can allow researchers to streamline the synthesis of new materials as well as control their propertie ...

EPFL2019

Structural disorder and magnetic correlations driven by oxygen doping in Nd2NiO4+delta (delta similar to 0.11)

We investigated the influence of oxygen overstoichiometry on apical oxygen disorder and magnetic correlations in Nd2NiO4+delta (delta similar to 0.11) in the temperature range of 2-300 K by means of synchrotron x-ray powder diffraction, neutron single-crys ...

AMER PHYSICAL SOC2019

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