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This thesis describes new methods for the detection of 14N nuclei by solid-state nuclear magnetic resonance. So far, the low natural abundance (0.4 %) 15N isotope has been widely used to study nitrogen-containing samples because of its spin-1/2 nature. The ...
The tetradentate chelate ligand tris[(1-vinylimidazol-2-yl)methyl]amine (10) was synthesized in five steps from commercially available starting materials. Upon reaction with MCl2 (M = Zn, Cu, Ni, Co) in the presence of NH4PF6, the complexes [M(10)Cl]PF6 (M ...
Despite the powerful spectroscopic information it provides, Nuclear Magnetic Resonance (NMR) spectroscopy suffers from a lack of sensitivity, especially when dealing with nuclei other than protons. Even though NMR can be applied in a straightforward manner ...
Nowadays, light emitting diodes (LEDs) and laser diodes (LDs) are part of our daily life. More and more devices incorporate InGaN-based optoelectronic devices. In fact, since the first demonstration of a candela-class InGaN-based LED in the beginning of th ...
An R&D program at CRPP investigates the design of large size Nb3Sn conductors, with the aim to improve the effectiveness and hence the cost of large size, force flow conductors. A design based on a solder filled flat cable, by react wind method, is selecte ...
The three-dimensional (3-D) VMEC code has been modified to model an energetic species with a variant of a Bi-Maxwellian distribution function that satisfies the constraint B . del F-h = 0, and the 3-D TERPSICHORE stability code has been extended to investi ...
Gallium Nitride (GaN) and its ternary alloys with aluminium and indium have met a growing interest in the last decade. These semiconductors have a large direct bandgap and can be doped with either silicon (Si) for n-type and magnesium (Mg) for p-type layer ...
Internal motions in proteins, such as oscillations of internuclear vectors u(NiHiN) of amide bonds about their equil. position, can be characterized by a local order parameter. This dynamic parameter can be detd. exptl. by measuring the longitudinal and tr ...
A phenomenological modelling approach has been developed to describe the massive transformation and the formation of lamellar microstructures during cooling in binary gamma titanium aluminides. The modelling approach is based on a combination of nucleation ...
