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This thesis describes new methods for the detection of 14N nuclei by solid-state nuclear magnetic resonance. So far, the low natural abundance (0.4 %) 15N isotope has been widely used to study nitrogen-containing samples because of its spin-1/2 nature. The ...
A phenomenological modelling approach has been developed to describe the massive transformation and the formation of lamellar microstructures during cooling in binary gamma titanium aluminides. The modelling approach is based on a combination of nucleation ...
An R&D program at CRPP investigates the design of large size Nb3Sn conductors, with the aim to improve the effectiveness and hence the cost of large size, force flow conductors. A design based on a solder filled flat cable, by react wind method, is selecte ...
The three-dimensional (3-D) VMEC code has been modified to model an energetic species with a variant of a Bi-Maxwellian distribution function that satisfies the constraint B . del F-h = 0, and the 3-D TERPSICHORE stability code has been extended to investi ...
The tetradentate chelate ligand tris[(1-vinylimidazol-2-yl)methyl]amine (10) was synthesized in five steps from commercially available starting materials. Upon reaction with MCl2 (M = Zn, Cu, Ni, Co) in the presence of NH4PF6, the complexes [M(10)Cl]PF6 (M ...
Gallium Nitride (GaN) and its ternary alloys with aluminium and indium have met a growing interest in the last decade. These semiconductors have a large direct bandgap and can be doped with either silicon (Si) for n-type and magnesium (Mg) for p-type layer ...
Internal motions in proteins, such as oscillations of internuclear vectors u(NiHiN) of amide bonds about their equil. position, can be characterized by a local order parameter. This dynamic parameter can be detd. exptl. by measuring the longitudinal and tr ...
Nowadays, light emitting diodes (LEDs) and laser diodes (LDs) are part of our daily life. More and more devices incorporate InGaN-based optoelectronic devices. In fact, since the first demonstration of a candela-class InGaN-based LED in the beginning of th ...
Despite the powerful spectroscopic information it provides, Nuclear Magnetic Resonance (NMR) spectroscopy suffers from a lack of sensitivity, especially when dealing with nuclei other than protons. Even though NMR can be applied in a straightforward manner ...