CarboraneCarboranes are electron-delocalized (non-classically bonded) clusters composed of boron, carbon and hydrogen atoms. Like many of the related boron hydrides, these clusters are polyhedra or fragments of polyhedra. Carboranes are one class of heteroboranes. In terms of scope, carboranes can have as few as 5 and as many as 14 atoms in the cage framework. The majority have two cage carbon atoms. The corresponding C-alkyl and B-alkyl analogues are also known in a few cases.
BoranesA borane is a compound with the formula BxHy or a related anion. Many such boranes are known. Most common are those with 1 to 12 boron atoms. Although they have few practical applications, the boranes exhibit structures and bonding that differs strongly from the patterns seen in hydrocarbons. Hybrids of boranes and hydrocarbons, the carboranes are also well developed. The development of the chemistry of boranes led to innovations in synthetic methods as well as structure and bonding.
NanoclusterNanoclusters are atomically precise, crystalline materials most often existing on the 0-2 nanometer scale. They are often considered kinetically stable intermediates that form during the synthesis of comparatively larger materials such as semiconductor and metallic nanocrystals. The majority of research conducted to study nanoclusters has focused on characterizing their crystal structures and understanding their role in the nucleation and growth mechanisms of larger materials.
Regular icosahedronIn geometry, a regular icosahedron (ˌaɪkɒsəˈhiːdrən,-kə-,-koʊ- or aɪˌkɒsəˈhiːdrən) is a convex polyhedron with 20 faces, 30 edges and 12 vertices. It is one of the five Platonic solids, and the one with the most faces. It has five equilateral triangular faces meeting at each vertex. It is represented by its Schläfli symbol {3,5}, or sometimes by its vertex figure as 3.3.3.3.3 or 35. It is the dual of the regular dodecahedron, which is represented by {5,3}, having three pentagonal faces around each vertex.
AntiprismIn geometry, an n-gonal antiprism or n-antiprism is a polyhedron composed of two parallel direct copies (not mirror images) of an n-sided polygon, connected by an alternating band of 2n triangles. They are represented by the Conway notation An. Antiprisms are a subclass of prismatoids, and are a (degenerate) type of snub polyhedron. Antiprisms are similar to prisms, except that the bases are twisted relatively to each other, and that the side faces (connecting the bases) are 2n triangles, rather than n quadrilaterals.
