Oxyhydrogen is a mixture of hydrogen (H2) and oxygen (O2) gases. This gaseous mixture is used for torches to process refractory materials and was the first
gaseous mixture used for welding. Theoretically, a ratio of 2:1 hydrogen:oxygen is enough to achieve maximum efficiency; in practice a ratio 4:1 or 5:1 is needed to avoid an oxidizing flame.
This mixture may also be referred to as Knallgas (Scandinavian and German ; ), although some authors define knallgas to be a generic term for the mixture of fuel with the precise amount of oxygen required for complete combustion, thus 2:1 oxyhydrogen would be called "hydrogen-knallgas".
"Brown's gas" and HHO are terms for oxyhydrogen mainly encountered in fringe science.
Oxyhydrogen will combust when brought to its autoignition temperature. For the stoichiometric mixture in air, at normal atmospheric pressure, autoignition occurs at about 570 °C (1065 °F). The minimum energy required to ignite such a mixture, at lower temperatures, with a spark is about 20 microjoules. At standard temperature and pressure, oxyhydrogen can burn when it is between about 4% and 95% hydrogen by volume.
When ignited, the gas mixture converts to water vapor and releases energy, which sustains the reaction: 241.8 kJ of energy (LHV) for every mole of burned. The amount of heat energy released is independent of the mode of combustion, but the temperature of the flame varies. The maximum temperature of about is achieved with an exact stoichiometric mixture, about hotter than a hydrogen flame in air.
When either of the gases are mixed in excess of this ratio, or when mixed with an inert gas like nitrogen, the heat must spread throughout a greater quantity of matter and the flame temperature will be lower.
A pure stoichiometric mixture may be obtained by water electrolysis, which uses an electric current to dissociate the water molecules:
Electrolysis:
Combustion:
William Nicholson was the first to decompose water in this manner in 1800. In theory, the input energy of a closed system always equals the output energy, as the first law of thermodynamics states.
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Electrolysis of water is using electricity to split water into oxygen (O2) and hydrogen (H2) gas by electrolysis. Hydrogen gas released in this way can be used as hydrogen fuel, but must be kept apart from the oxygen as the mixture would be extremely explosive. Separately pressurised into convenient 'tanks' or 'gas bottles', hydrogen can be used for oxyhydrogen welding and other applications, as the hydrogen / oxygen flame can reach circa 2,800°C. Water electrolysis requires a minimum potential difference of 1.
A fuel is any material that can be made to react with other substances so that it releases energy as thermal energy or to be used for work. The concept was originally applied solely to those materials capable of releasing chemical energy but has since also been applied to other sources of heat energy, such as nuclear energy (via nuclear fission and nuclear fusion). The heat energy released by reactions of fuels can be converted into mechanical energy via a heat engine.
Hydrogen fuel refers to hydrogen which is burned as fuel with pure oxygen (not to be confused with atmospheric gases). It can be a zero-carbon fuel, provided that it is created in a process that does not involve carbon. However, most hydrogen comes from fossil fuels, resulting in carbon dioxide emissions. Depending on the source and the resulting environmental impact, hydrogen that is sourced from various methods can be referred to by a variety of terms using metaphorical names of colors: white, green, blue, grey, black, or brown hydrogen.
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