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Surface Charge Boundary Condition Often Misused in CO2 Reduction Models

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The Poisson-Nernst-Planck equations have been used to model species transport in electrochemical CO2 reduction, where the surface charge boundary condition accounts for the potential drop across the Stern layer. A direct comparison of the published models ...
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Electrokinetic, electrochemical, and electrostatic surface potentials of the pristine water liquid-vapor interface

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Although conceptually simple, the air-water interface displays rich behavior and is subject to intense experimental and theoretical investigations. Different definitions of the electrostatic surface potential as well as different calculation methods, each ...
AIP Publishing2022

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